{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Hu NH"],"funding":["Bowling Green State University"],"pagination":["E1849"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC7215510"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["13(8)"],"pubmed_abstract":["Silsesquioxane-based networks are an important class of materials that have many applications where high thermal/oxidative stability and porosity are needed simultaneously. However, there is a great desire to be able to design these materials for specialized applications in environmental remediation and medicine. To do so requires a simple synthesis method to make materials with expanded functionalities. In this article, we explore the synthesis of R-silsesquioxane-based porous networks by fluoride catalysis containing methyl, phenyl and vinyl corners (R-Si(OEt)3) combined with four different bis-triethoxysilyl cross-linkers (ethyl, ethylene, acetylene and hexyl). Synthesized materials were then analyzed for their porosity, surface area, thermal stability and general structure. We found th"],"journal":["Materials (Basel, Switzerland)"],"pubmed_title":["R-Silsesquioxane-Based Network Polymers by Fluoride Catalyzed Synthesis: An Investigation of Cross-Linker Structure and Its Influence on Porosity."],"pmcid":["PMC7215510"],"funding_grant_id":["Startup Funding"],"pubmed_authors":["Hu NH","Furgal JC"],"additional_accession":[]},"is_claimable":false,"name":"R-Silsesquioxane-Based Network Polymers by Fluoride Catalyzed Synthesis: An Investigation of Cross-Linker Structure and Its Influence on Porosity.","description":"Silsesquioxane-based networks are an important class of materials that have many applications where high thermal/oxidative stability and porosity are needed simultaneously. However, there is a great desire to be able to design these materials for specialized applications in environmental remediation and medicine. To do so requires a simple synthesis method to make materials with expanded functionalities. In this article, we explore the synthesis of R-silsesquioxane-based porous networks by fluoride catalysis containing methyl, phenyl and vinyl corners (R-Si(OEt)3) combined with four different bis-triethoxysilyl cross-linkers (ethyl, ethylene, acetylene and hexyl). Synthesized materials were then analyzed for their porosity, surface area, thermal stability and general structure. We found th","dates":{"release":"2020-01-01T00:00:00Z","publication":"2020 Apr","modification":"2025-04-25T21:48:49.485Z","creation":"2020-05-26T07:06:43Z"},"accession":"S-EPMC7215510","cross_references":{"pubmed":["32326565"],"doi":["10.3390/ma13081849"]}}