biostudies-literatureNazim MEnergy Technology Development Program16106-16119https://www.ebi.ac.uk/biostudies/studies/S-EPMC7346233biostudies-literatureUnknown5(26)Organometallic halide perovskites, as the light-harvesting material, have been extensively used for cost-effective energy production in high-performance perovskite solar cells, despite their poor stability in the ambient atmosphere. In this work, methylammonium lead iodide, CH₃NH₃PbI₃, perovskite was successfully doped with KMnO₄ using antisolvent crystallization to develop micrometer-length perovskite microrods. Thus, the obtained KMnO₄-doped perovskite microrods have exhibited sharp, narrow, and red-shifted photoluminescence band, as well as high lattice strain with improved thermal stability compared to undoped CH₃NH₃PbI₃. During the synthesis of the KMnO₄-doped perovskite microrods, a lowACS omegaControlled Size Growth of Thermally Stable Organometallic Halide Perovskite Microrods: Synergistic Effect of Dual-Doping, Lattice Strain Engineering, Antisolvent Crystallization, and Band Gap Tuning Properties.PMC734623320173010012880Kim JHNazim MfalseControlled Size Growth of Thermally Stable Organometallic Halide Perovskite Microrods: Synergistic Effect of Dual-Doping, Lattice Strain Engineering, Antisolvent Crystallization, and Band Gap Tuning Properties.Organometallic halide perovskites, as the light-harvesting material, have been extensively used for cost-effective energy production in high-performance perovskite solar cells, despite their poor stability in the ambient atmosphere. In this work, methylammonium lead iodide, CH₃NH₃PbI₃, perovskite was successfully doped with KMnO₄ using antisolvent crystallization to develop micrometer-length perovskite microrods. Thus, the obtained KMnO₄-doped perovskite microrods have exhibited sharp, narrow, and red-shifted photoluminescence band, as well as high lattice strain with improved thermal stability compared to undoped CH₃NH₃PbI₃. During the synthesis of the KMnO₄-doped perovskite microrods, a low2020-01-01T00:00:00Z2020 Jul2025-04-22T19:35:36.582Z2025-04-06T02:46:43.213ZS-EPMC73462333265643310.1021/acsomega.0c01667