{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Wang L"],"funding":["National Institute of General Medical Sciences","NIGMS NIH HHS"],"pagination":["1811-1821"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC7375339"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["142(4)"],"pubmed_abstract":["In coordination-driven self-assembly, 2,2':6',2″-terpyridine (tpy) has gained extensive attention in constructing supramolecular architectures on the basis of ⟨tpy-M-tpy⟩ connectivity. In direct self-assembly of large discrete structures, however, the metal ions were mainly limited to Cd(II), Zn(II), and Fe(II) ions. Herein, we significantly broaden the spectrum of metal ions with seven divalent transition metal ions M(II) (M = Mn, Fe, Co, Ni, Cu, Zn, Cd) to assemble a series of supramolecular fractals. In particular, Mn(II), Co(II), Ni(II), and Cu(II) were reported for the first time to form such large and discrete structures with ⟨tpy-M-tpy⟩ connectivity. In addition, the structural stabilities of those supramolecules in the gas phase and the kinetics of the ligand exchange process in so"],"journal":["Journal of the American Chemical Society"],"pubmed_title":["Introducing Seven Transition Metal Ions into Terpyridine-Based Supramolecules: Self-Assembly and Dynamic Ligand Exchange Study."],"pmcid":["PMC7375339"],"funding_grant_id":["R01 GM128037","1R01GM128037"],"pubmed_authors":["Wang M","Li X","Li Y","Bai S","Ming LJ","Khalife S","Song B","Wang H","Yu H","Wang L","Xu Y"],"additional_accession":[]},"is_claimable":false,"name":"Introducing Seven Transition Metal Ions into Terpyridine-Based Supramolecules: Self-Assembly and Dynamic Ligand Exchange Study.","description":"In coordination-driven self-assembly, 2,2':6',2″-terpyridine (tpy) has gained extensive attention in constructing supramolecular architectures on the basis of ⟨tpy-M-tpy⟩ connectivity. In direct self-assembly of large discrete structures, however, the metal ions were mainly limited to Cd(II), Zn(II), and Fe(II) ions. Herein, we significantly broaden the spectrum of metal ions with seven divalent transition metal ions M(II) (M = Mn, Fe, Co, Ni, Cu, Zn, Cd) to assemble a series of supramolecular fractals. In particular, Mn(II), Co(II), Ni(II), and Cu(II) were reported for the first time to form such large and discrete structures with ⟨tpy-M-tpy⟩ connectivity. In addition, the structural stabilities of those supramolecules in the gas phase and the kinetics of the ligand exchange process in so","dates":{"release":"2020-01-01T00:00:00Z","publication":"2020 Jan","modification":"2025-04-19T11:38:31.055Z","creation":"2025-04-19T11:38:31.055Z"},"accession":"S-EPMC7375339","cross_references":{"pubmed":["31910337"],"doi":["10.1021/jacs.9b09497"]}}