{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["26(37)"],"submitter":["Antoni PW"],"pubmed_abstract":["A sulfilimine-based Group 9 transition-metal-catalysed C-H amidation procedure is reported. Dibenzothiophene-based sulfilimines were shown to constitute a class of novel amidation reagents which enable the transfer of a wide range of N-sulfonyl and N-acyl moieties. It was demonstrated that sulfilimines, which are easily accessible from cheap reagents, are safe-to-handle and represent broadly applicable amidation reagents. The dibenzothiophene can be recycled after use. The C-H amidation was shown to proceed with high selectivity and gave the mono-amidated products, mostly in good to excellent yields."],"journal":["Chemistry (Weinheim an der Bergstrasse, Germany)"],"pagination":["8235-8238"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC7383884"],"repository":["biostudies-literature"],"pubmed_title":["Dibenzothiophenesulfilimines: A Convenient Approach to Intermolecular Rhodium-Catalysed C-H Amidation."],"pmcid":["PMC7383884"],"pubmed_authors":["Mackenroth AV","Mulks FF","Helmchen G","Rudolph M","Antoni PW","Hashmi ASK"],"additional_accession":[]},"is_claimable":false,"name":"Dibenzothiophenesulfilimines: A Convenient Approach to Intermolecular Rhodium-Catalysed C-H Amidation.","description":"A sulfilimine-based Group 9 transition-metal-catalysed C-H amidation procedure is reported. Dibenzothiophene-based sulfilimines were shown to constitute a class of novel amidation reagents which enable the transfer of a wide range of N-sulfonyl and N-acyl moieties. It was demonstrated that sulfilimines, which are easily accessible from cheap reagents, are safe-to-handle and represent broadly applicable amidation reagents. The dibenzothiophene can be recycled after use. The C-H amidation was shown to proceed with high selectivity and gave the mono-amidated products, mostly in good to excellent yields.","dates":{"release":"2020-01-01T00:00:00Z","publication":"2020 Jul","modification":"2025-04-19T23:03:22.918Z","creation":"2025-04-19T23:03:22.918Z"},"accession":"S-EPMC7383884","cross_references":{"pubmed":["32428332"],"doi":["10.1002/chem.202002371"]}}