{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Horii Y"],"funding":["National University of Singapore","Core Research for Evolutional Science and Technology","Tohoku University Molecule & Material Synthesis Platform in Nanotechnology Platform Project","Baden-Württemberg","German-Japanese University Consortium","Centro de Investigación Biomédica en Red en Bioingeniería, Biomateriales y Nanomedicina","state of Baden-Württemberg through bwHPC and the German Research Foundation (DFG) through grant No. INST 40/467-1 FUGG.","European Commission","Higher Education Discipline Innovation Project","Generalitat de Catalunya","Deutsche Forschungsgemeinschaft","European Research Council","Beilstein-Institut zur Förderung der Chemischen Wissenschaften","Ministerio de Economía y Competitividad","Japan Society for the Promotion of Science"],"pagination":["8621-8630"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC7384013"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["26(39)"],"pubmed_abstract":["Presented here is a comprehensive study of highly oxidized multiple-decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands, which are stabilized by electron-donating n-butoxy groups. From X-ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl-shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4e charged species. From paramagnetic 1 H NMR studies on the resulting series of triple, quadruple and quintuple-decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2e charge"],"journal":["Chemistry (Weinheim an der Bergstrasse, Germany)"],"pubmed_title":["Highly Oxidized States of Phthalocyaninato Terbium(III) Multiple-Decker Complexes Showing Structural Deformations, Biradical Properties and Decreases in Magnetic Anisotropy."],"pmcid":["PMC7384013"],"funding_grant_id":["SEV-2015-0496","FANCY CTQ2016-80030-R","306826","2017SGR918","B18030","JP14J02656","ERC StG 2012-306826","JP20225003","JPMJCR12L3","INST 40/467-1 FUGG","18K14242","JP15K05467","R-143-000-A65-133","JP24750119","R-143-000-A80-114","19K05401","MAT2016-80826-R","JP17K19102","bwHPC"],"pubmed_authors":["Kitagawa Y","Horii Y","Breedlove BK","Mas-Torrent M","Chibotaru L","Wernsdorfer W","Ajayakumar MR","Katoh K","Damjanovic M","Veciana J","Ungur L","Enders M","Yamashita M"],"additional_accession":[]},"is_claimable":false,"name":"Highly Oxidized States of Phthalocyaninato Terbium(III) Multiple-Decker Complexes Showing Structural Deformations, Biradical Properties and Decreases in Magnetic Anisotropy.","description":"Presented here is a comprehensive study of highly oxidized multiple-decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands, which are stabilized by electron-donating n-butoxy groups. From X-ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl-shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4e charged species. From paramagnetic 1 H NMR studies on the resulting series of triple, quadruple and quintuple-decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2e charge","dates":{"release":"2020-01-01T00:00:00Z","publication":"2020 Jul","modification":"2025-04-19T23:01:23.947Z","creation":"2025-04-19T23:01:23.947Z"},"accession":"S-EPMC7384013","cross_references":{"pubmed":["32428358"],"doi":["10.1002/chem.202001365"]}}