{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["8"],"submitter":["Fujiki M"],"funding":["Ministry of Higher Education, Malaysia","Japan Society for the Promotion of Science"],"pubmed_abstract":["We report emerging circularly polarized luminescence (CPL) at 4<i>f-</i>4<i>f</i> transitions when lanthanide (Eu<sup>III</sup> and Tb<sup>III</sup>) tris(β-diketonate) embedded to cellulose triacetate (<b>CTA</b>), cellulose acetate butyrate (<b>CABu</b>), <i>D</i>-/<i>L</i>-glucose pentamethyl esters ( <b><i>D</i>-</b>/ <b><i>L</i>-Glu</b>), and <i>D</i>-/<i>L</i>-arabinose tetramethyl esters ( <b><i>D</i>-</b>/ <b><i>L</i>-Ara</b>) are in film states. Herein, 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionate (fod) and 2,2,6,6-tetramethyl-3,5-heptanedione (dpm) were chosen as the β-diketonates. The <i>g</i> <sub>lum</sub> value of Eu(fod)<sub>3</sub> in <b>CABu</b> are +0.0671 at 593 nm (<sup>5</sup>  D 0  → 7   F<sub>1</sub>) and -0.0059 at 613 nm (<sup>5</sup>  D 0  → 7   F<sub>"],"journal":["Frontiers in chemistry"],"pagination":["685"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC7438854"],"repository":["biostudies-literature"],"pubmed_title":["Chirogenesis and Pfeiffer Effect in Optically Inactive Eu<sup>III</sup> and Tb<sup>III</sup> Tris(β-diketonate) Upon Intermolecular Chirality Transfer From Poly- and Monosaccharide Alkyl Esters and α-Pinene: Emerging Circularly Polarized Luminescence (CPL) and Circular Dichroism (CD)."],"pmcid":["PMC7438854"],"pubmed_authors":["Asanoma F","Jalilah AJ","Okubo A","Ogata N","Kamite H","Okazaki S","Fujiki M","Wang L"],"additional_accession":[]},"is_claimable":false,"name":"Chirogenesis and Pfeiffer Effect in Optically Inactive Eu<sup>III</sup> and Tb<sup>III</sup> Tris(β-diketonate) Upon Intermolecular Chirality Transfer From Poly- and Monosaccharide Alkyl Esters and α-Pinene: Emerging Circularly Polarized Luminescence (CPL) and Circular Dichroism (CD).","description":"We report emerging circularly polarized luminescence (CPL) at 4<i>f-</i>4<i>f</i> transitions when lanthanide (Eu<sup>III</sup> and Tb<sup>III</sup>) tris(β-diketonate) embedded to cellulose triacetate (<b>CTA</b>), cellulose acetate butyrate (<b>CABu</b>), <i>D</i>-/<i>L</i>-glucose pentamethyl esters ( <b><i>D</i>-</b>/ <b><i>L</i>-Glu</b>), and <i>D</i>-/<i>L</i>-arabinose tetramethyl esters ( <b><i>D</i>-</b>/ <b><i>L</i>-Ara</b>) are in film states. Herein, 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionate (fod) and 2,2,6,6-tetramethyl-3,5-heptanedione (dpm) were chosen as the β-diketonates. The <i>g</i> <sub>lum</sub> value of Eu(fod)<sub>3</sub> in <b>CABu</b> are +0.0671 at 593 nm (<sup>5</sup>  D 0  → 7   F<sub>1</sub>) and -0.0059 at 613 nm (<sup>5</sup>  D 0  → 7   F<sub>","dates":{"release":"2020-01-01T00:00:00Z","publication":"2020","modification":"2025-04-25T19:37:59.445Z","creation":"2020-09-13T07:03:09Z"},"accession":"S-EPMC7438854","cross_references":{"pubmed":["32903703"],"doi":["10.3389/fchem.2020.00685"]}}