biostudies-literatureUnknown8Fujiki MMinistry of Higher Education, MalaysiaJapan Society for the Promotion of ScienceWe report emerging circularly polarized luminescence (CPL) at 4<i>f-</i>4<i>f</i> transitions when lanthanide (Eu^III and Tb^III) tris(β-diketonate) embedded to cellulose triacetate (<b>CTA</b>), cellulose acetate butyrate (<b>CABu</b>), <i>D</i>-/<i>L</i>-glucose pentamethyl esters ( <b><i>D</i>-</b>/ <b><i>L</i>-Glu</b>), and <i>D</i>-/<i>L</i>-arabinose tetramethyl esters ( <b><i>D</i>-</b>/ <b><i>L</i>-Ara</b>) are in film states. Herein, 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionate (fod) and 2,2,6,6-tetramethyl-3,5-heptanedione (dpm) were chosen as the β-diketonates. The <i>g</i> _lum value of Eu(fod)₃ in <b>CABu</b> are +0.0671 at 593 nm (⁵ D 0 → 7 F₁) and -0.0059 at 613 nm (⁵ D 0 → 7 F<sub>Frontiers in chemistry685https://www.ebi.ac.uk/biostudies/studies/S-EPMC7438854biostudies-literatureChirogenesis and Pfeiffer Effect in Optically Inactive Eu^III and Tb^III Tris(β-diketonate) Upon Intermolecular Chirality Transfer From Poly- and Monosaccharide Alkyl Esters and α-Pinene: Emerging Circularly Polarized Luminescence (CPL) and Circular Dichroism (CD).PMC7438854Asanoma FJalilah AJOkubo AOgata NKamite HOkazaki SFujiki MWang LfalseChirogenesis and Pfeiffer Effect in Optically Inactive Eu^III and Tb^III Tris(β-diketonate) Upon Intermolecular Chirality Transfer From Poly- and Monosaccharide Alkyl Esters and α-Pinene: Emerging Circularly Polarized Luminescence (CPL) and Circular Dichroism (CD).We report emerging circularly polarized luminescence (CPL) at 4<i>f-</i>4<i>f</i> transitions when lanthanide (Eu^III and Tb^III) tris(β-diketonate) embedded to cellulose triacetate (<b>CTA</b>), cellulose acetate butyrate (<b>CABu</b>), <i>D</i>-/<i>L</i>-glucose pentamethyl esters ( <b><i>D</i>-</b>/ <b><i>L</i>-Glu</b>), and <i>D</i>-/<i>L</i>-arabinose tetramethyl esters ( <b><i>D</i>-</b>/ <b><i>L</i>-Ara</b>) are in film states. Herein, 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionate (fod) and 2,2,6,6-tetramethyl-3,5-heptanedione (dpm) were chosen as the β-diketonates. The <i>g</i> _lum value of Eu(fod)₃ in <b>CABu</b> are +0.0671 at 593 nm (⁵ D 0 → 7 F₁) and -0.0059 at 613 nm (⁵ D 0 → 7 F<sub>2020-01-01T00:00:00Z20202025-04-25T19:37:59.445Z2020-09-13T07:03:09ZS-EPMC74388543290370310.3389/fchem.2020.00685