{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Levchenko V"],"funding":["Norges Forskningsråd"],"pagination":["1725-1727"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC7643232"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["76(Pt 11)"],"pubmed_abstract":["The title compound, an (N^C)-cyclo-metalated gold(III) diazide, namely, di-azido-[5-eth-oxy-carbonyl-2-(5-eth-oxy-carbonyl-pyridin-2-yl)phenyl-κ<sup>2</sup> <i>C</i> <sup>1</sup>,<i>N</i>]gold(III), [Au(C<sub>17</sub>H<sub>16</sub>NO<sub>4</sub>)(N<sub>3</sub>)<sub>2</sub>] or Au(ppy<sup>Et</sup>)(N<sub>3</sub>)<sub>2</sub>, was synthesized by reacting Au(ppy<sup>Et</sup>)Cl<sub>2</sub> with NaN<sub>3</sub> in water for 24 h. The complex has been structurally characterized and features a gold center with a square-planar environment. The Au-N(azide) bond lengths are significantly different depending on the influence of the atom <i>trans</i> to the azide group [Au-N(<i>trans</i> to C) of 2.067 (2) Å <i>versus</i> Au-N(<i>trans</i> to N) of 2.042 (2) Å]. The azide groups are twisted in-and-ou"],"journal":["Acta crystallographica. Section E, Crystallographic communications"],"pubmed_title":["Crystal structure of (N^C) cyclo-metalated Au<sup>III</sup> diazide at 100 K."],"pmcid":["PMC7643232"],"funding_grant_id":["250795"],"pubmed_authors":["Oien-Odegaard S","Levchenko V","Wragg D","Tilset M"],"additional_accession":[]},"is_claimable":false,"name":"Crystal structure of (N^C) cyclo-metalated Au<sup>III</sup> diazide at 100 K.","description":"The title compound, an (N^C)-cyclo-metalated gold(III) diazide, namely, di-azido-[5-eth-oxy-carbonyl-2-(5-eth-oxy-carbonyl-pyridin-2-yl)phenyl-κ<sup>2</sup> <i>C</i> <sup>1</sup>,<i>N</i>]gold(III), [Au(C<sub>17</sub>H<sub>16</sub>NO<sub>4</sub>)(N<sub>3</sub>)<sub>2</sub>] or Au(ppy<sup>Et</sup>)(N<sub>3</sub>)<sub>2</sub>, was synthesized by reacting Au(ppy<sup>Et</sup>)Cl<sub>2</sub> with NaN<sub>3</sub> in water for 24 h. The complex has been structurally characterized and features a gold center with a square-planar environment. The Au-N(azide) bond lengths are significantly different depending on the influence of the atom <i>trans</i> to the azide group [Au-N(<i>trans</i> to C) of 2.067 (2) Å <i>versus</i> Au-N(<i>trans</i> to N) of 2.042 (2) Å]. The azide groups are twisted in-and-ou","dates":{"release":"2020-01-01T00:00:00Z","publication":"2020 Nov","modification":"2025-05-29T19:37:03.591Z","creation":"2025-05-29T19:37:03.591Z"},"accession":"S-EPMC7643232","cross_references":{"pubmed":["33209341"],"doi":["10.1107/S2056989020012955"]}}