biostudies-literatureUnknown76(Pt 11)Tanaka TThe title crystalline compound, [Cu₂(NCS)₂(C₉H₁₆N₂)₂], was obtained from the reaction of copper(I) thio-cyanate (CuSCN) with (<i>N</i>-prop-2-en-1-yl)piperidine-1-carbo-thio-amide as a chelating and bridging thio-urea ligand in chloro-benzene. The Cu₂S₂ core of the dimeric mol-ecule is situated on a crystallographic inversion centre. The copper atom is coordinated by a thio-cyanate nitro-gen atom, each sulfur atom of the two thio-urea ligands, and the C=C double bond of the ligand in a distorted tetra-hedral geometry. The dimers are linked by N-H⋯S hydrogen bonds, forming a network extending in two dimensions parallel to (100).Acta crystallographica. Section E, Crystallographic communications1712-1715https://www.ebi.ac.uk/biostudies/studies/S-EPMC7643236biostudies-literatureCrystal structure of bis-[μ-<i>N</i>-(η²-prop-2-en-1-yl)piperidine-1-carbo-thio-amide-κ² <i>S</i>:<i>S</i>]bis-[(thio-cyanato-κ<i>N</i>)copper(I)].PMC7643236Nakagawa MKashiwagi YTanaka TfalseCrystal structure of bis-[μ-<i>N</i>-(η²-prop-2-en-1-yl)piperidine-1-carbo-thio-amide-κ² <i>S</i>:<i>S</i>]bis-[(thio-cyanato-κ<i>N</i>)copper(I)].The title crystalline compound, [Cu₂(NCS)₂(C₉H₁₆N₂)₂], was obtained from the reaction of copper(I) thio-cyanate (CuSCN) with (<i>N</i>-prop-2-en-1-yl)piperidine-1-carbo-thio-amide as a chelating and bridging thio-urea ligand in chloro-benzene. The Cu₂S₂ core of the dimeric mol-ecule is situated on a crystallographic inversion centre. The copper atom is coordinated by a thio-cyanate nitro-gen atom, each sulfur atom of the two thio-urea ligands, and the C=C double bond of the ligand in a distorted tetra-hedral geometry. The dimers are linked by N-H⋯S hydrogen bonds, forming a network extending in two dimensions parallel to (100).2020-01-01T00:00:00Z2020 Nov2024-11-06T05:29:39.575Z2020-11-22T09:39:19ZS-EPMC76432363320933810.1107/S2056989020013146