biostudies-literature00480da Camara BDivision of ChemistryNational Institute of General Medical SciencesNIGMS NIH HHS14263-14266https://www.ebi.ac.uk/biostudies/studies/S-EPMC7674236biostudies-literatureUnknown56(91)A spacious Fe(ii)-iminopyridine self-assembled cage complex can catalyze the oxidative dimerization of alkanethiols, with air as stoichiometric oxidant. The reaction is aided by selective molecular recognition of the reactants, and the active catalyst is derived from the Fe(ii) centers that provide the structural vertices of the host. The host is even capable of size-selective oxidation and can discriminate between alkanethiols of identical reactivity, based solely on size.Chemical communications (Cambridge, England)Selective, cofactor-mediated catalytic oxidation of alkanethiols in a self-assembled cage host.PMC7674236R01 GM097569CHE-2002619GM097569CHE-1708019Mueller LJHooley RJda Camara BChalek KRDietz PC48falseSelective, cofactor-mediated catalytic oxidation of alkanethiols in a self-assembled cage host.A spacious Fe(ii)-iminopyridine self-assembled cage complex can catalyze the oxidative dimerization of alkanethiols, with air as stoichiometric oxidant. The reaction is aided by selective molecular recognition of the reactants, and the active catalyst is derived from the Fe(ii) centers that provide the structural vertices of the host. The host is even capable of size-selective oxidation and can discriminate between alkanethiols of identical reactivity, based solely on size.2020-01-01T00:00:00Z2020 Nov2024-11-20T02:36:56.881Z2022-02-11T13:09:06.895ZS-EPMC76742363312464110.1039/d0cc05765g