{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["60(4)"],"submitter":["Li B"],"pubmed_abstract":["Oxidative addition of cyclic alkyl(amino)carbene-coordinated phosphinidenes (<sup>Me</sup> cAAC)PX to LGa affords gallium-coordinated phosphinidenes LGa(X)-P(<sup>Me</sup> cAAC) (L=HC[C(Me)N(2,6-i-Pr<sub>2</sub> C<sub>6</sub> H<sub>3</sub> )]<sub>2</sub> ; X=Cl 1, Br 2), which react with NaBAr<sup>F</sup> <sub>4</sub> and LiAl(OR<sup>F</sup> )<sub>4</sub> to [LGaP(<sup>Me</sup> cAAC)][An] (An=B(C<sub>6</sub> H<sub>3</sub> (CF<sub>3</sub> )<sub>2</sub> )<sub>4</sub> 3, B(C<sub>6</sub> F<sub>5</sub> )<sub>4</sub> 4, Al(OC(CF<sub>3</sub> )<sub>3</sub> )<sub>4</sub> 5). The cations in 3-5 show substantial Ga-P double bond character and represent heteronuclear analogues of allyl cations according to quantum chemical calculations. The reaction of 4 with 4-dimethylaminopyridine (dmap) to adduct 6"],"journal":["Angewandte Chemie (International ed. in English)"],"pagination":["1986-1991"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC7894565"],"repository":["biostudies-literature"],"pubmed_title":["Synthesis and Reactivity of Heteroleptic Ga-P-C Allyl Cation Analogues."],"pmcid":["PMC7894565"],"pubmed_authors":["Wolper C","Haberhauer G","Schulz S","Li B"],"additional_accession":[]},"is_claimable":false,"name":"Synthesis and Reactivity of Heteroleptic Ga-P-C Allyl Cation Analogues.","description":"Oxidative addition of cyclic alkyl(amino)carbene-coordinated phosphinidenes (<sup>Me</sup> cAAC)PX to LGa affords gallium-coordinated phosphinidenes LGa(X)-P(<sup>Me</sup> cAAC) (L=HC[C(Me)N(2,6-i-Pr<sub>2</sub> C<sub>6</sub> H<sub>3</sub> )]<sub>2</sub> ; X=Cl 1, Br 2), which react with NaBAr<sup>F</sup> <sub>4</sub> and LiAl(OR<sup>F</sup> )<sub>4</sub> to [LGaP(<sup>Me</sup> cAAC)][An] (An=B(C<sub>6</sub> H<sub>3</sub> (CF<sub>3</sub> )<sub>2</sub> )<sub>4</sub> 3, B(C<sub>6</sub> F<sub>5</sub> )<sub>4</sub> 4, Al(OC(CF<sub>3</sub> )<sub>3</sub> )<sub>4</sub> 5). The cations in 3-5 show substantial Ga-P double bond character and represent heteronuclear analogues of allyl cations according to quantum chemical calculations. The reaction of 4 with 4-dimethylaminopyridine (dmap) to adduct 6","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021 Jan","modification":"2025-04-04T20:58:30.599Z","creation":"2021-03-05T09:07:40Z"},"accession":"S-EPMC7894565","cross_references":{"pubmed":["33034935"],"doi":["10.1002/anie.202012595"]}}