{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Yu MH"],"funding":["National Natural Science Foundation of China","Intramural NIST DOC","National Science Foundation"],"pagination":["17703-17712"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC7927981"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["141(44)"],"pubmed_abstract":["Physical adsorption of gas molecules in microporous materials is an exothermic process, with desorption entropy driving a decrease in uptake with temperature. Enhanced gas sorption with increasing temperature is rare in porous materials and is indicative of sorbate initiated structural change. Here, sorption of C<sub>2</sub>H<sub>6</sub>, C<sub>3</sub>H<sub>6</sub>, and C<sub>3</sub>H<sub>8</sub> in a flexible microporous metal-organic framework (MOF) {Cu(FPBDC)]·DMF}<sub><i>n</i></sub> (<b>NKU-FlexMOF-1</b>) (H<sub>2</sub>FPBDC = 5-(5-fluoropyridin-3-yl)-1,3-benzenedicarboxylic acid) that increases with rising temperature over a practically useful temperature and pressure range is reported along with other small molecule and hydrocarbon sorption isotherms. Single X-ray diffraction studies"],"journal":["Journal of the American Chemical Society"],"pubmed_title":["Enhanced Gas Uptake in a Microporous Metal-Organic Framework &lt;i&gt;via&lt;/i&gt; a Sorbate Induced-Fit Mechanism."],"pmcid":["PMC7927981"],"funding_grant_id":["21421001","21531005","DMR-1607989","21673120","9185612","9999-NIST","CHE-1531590","21606163"],"pubmed_authors":["Li W","Space B","Franz D","He C","Yu MH","Krishna R","Hu TL","Zhou W","Bu XH","Chang Z","Li L"],"additional_accession":[]},"is_claimable":false,"name":"Enhanced Gas Uptake in a Microporous Metal-Organic Framework &lt;i&gt;via&lt;/i&gt; a Sorbate Induced-Fit Mechanism.","description":"Physical adsorption of gas molecules in microporous materials is an exothermic process, with desorption entropy driving a decrease in uptake with temperature. Enhanced gas sorption with increasing temperature is rare in porous materials and is indicative of sorbate initiated structural change. Here, sorption of C<sub>2</sub>H<sub>6</sub>, C<sub>3</sub>H<sub>6</sub>, and C<sub>3</sub>H<sub>8</sub> in a flexible microporous metal-organic framework (MOF) {Cu(FPBDC)]·DMF}<sub><i>n</i></sub> (<b>NKU-FlexMOF-1</b>) (H<sub>2</sub>FPBDC = 5-(5-fluoropyridin-3-yl)-1,3-benzenedicarboxylic acid) that increases with rising temperature over a practically useful temperature and pressure range is reported along with other small molecule and hydrocarbon sorption isotherms. Single X-ray diffraction studies","dates":{"release":"2019-01-01T00:00:00Z","publication":"2019 Nov","modification":"2026-05-08T15:23:56.164Z","creation":"2021-03-06T08:10:24Z"},"accession":"S-EPMC7927981","cross_references":{"pubmed":["31603672"],"doi":["10.1021/jacs.9b07807"]}}