{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Kuliga J"],"funding":["Deutscher Akademischer Austauschdienst","São Paulo Research Foundation (FAPESP)","Collaborative Research Center SFB 953","German Research Foundation (DFG)","Friedrich-Alexander-Universität Erlangen-Nürnberg","CAPES (Brazil)","Brazilian-German collaborative project PROBRAL","DAAD"],"pagination":["396-403"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC7986197"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["22(4)"],"pubmed_abstract":["We study the interaction and metalation reaction of a free base 5,10,15,20-terakis(4-cyanophenyl)porphyrin (2HTCNPP) with post-deposited Zn atoms and the targeted reaction product Zn-5,10,15,20-terakis(4-cyanophenyl)porphyrin (ZnTCNPP) on a Ag(111) surface. The investigations are performed with scanning tunneling microscopy at room temperature after Zn deposition and subsequent heating. The goal is to obtain further insights in the metalation reaction and the influence of the cyanogroups on this reaction. The interaction of 2HTCNPP with post-deposited Zn leads to the formation of three different 2D ordered island types that coexist on the surface. All contain a new species with a bright appearance, which increases with the amount of post-deposited Zn. We attribute this to metastable SAT (\""],"journal":["Chemphyschem : a European journal of chemical physics and physical chemistry"],"pubmed_title":["Metalation of 2HTCNPP on Ag(111) with Zn: Evidence for the Sitting atop Complex at Room Temperature."],"pmcid":["PMC7986197"],"funding_grant_id":["FOR 1878 (funCOS)","1925/2016","2007/54829-5","182849149","2007/08244-5"],"pubmed_authors":["Jux N","Steinruck HP","Lepper M","Marbach H","de Siervo A","Massicot S","de Campos Ferreirra RC","Holzel H","Kuliga J","Adhikari R"],"additional_accession":[]},"is_claimable":false,"name":"Metalation of 2HTCNPP on Ag(111) with Zn: Evidence for the Sitting atop Complex at Room Temperature.","description":"We study the interaction and metalation reaction of a free base 5,10,15,20-terakis(4-cyanophenyl)porphyrin (2HTCNPP) with post-deposited Zn atoms and the targeted reaction product Zn-5,10,15,20-terakis(4-cyanophenyl)porphyrin (ZnTCNPP) on a Ag(111) surface. The investigations are performed with scanning tunneling microscopy at room temperature after Zn deposition and subsequent heating. The goal is to obtain further insights in the metalation reaction and the influence of the cyanogroups on this reaction. The interaction of 2HTCNPP with post-deposited Zn leads to the formation of three different 2D ordered island types that coexist on the surface. All contain a new species with a bright appearance, which increases with the amount of post-deposited Zn. We attribute this to metastable SAT (\"","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021 Feb","modification":"2025-04-05T15:26:40.624Z","creation":"2024-11-21T04:50:59.917Z"},"accession":"S-EPMC7986197","cross_references":{"pubmed":["33285027"],"doi":["10.1002/cphc.202000883"]}}