{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["60(12)"],"submitter":["Hagspiel S"],"funding":["Studienstiftung des Deutschen Volkes","Deutsche Forschungsgemeinschaft","Alexander von Humboldt-Stiftung","Coordenação de Aperfeiçoamento de Pessoal de Nível Superior"],"pubmed_abstract":["Reduction of (CAAC)BBr<sub>2</sub> (NCS) (CAAC=cyclic alkyl(amino)carbene) in the presence of a Lewis base L yields tricoordinate (CAAC)LB(NCS) borylenes which undergo reversible E/Z-isomerization. The same reduction in the absence of L yields deep blue, bis(CAAC)-stabilized, boron-doped, aromatic thiazolothiazoles resulting from the dimerization of dicoordinate (CAAC)B(NCS) borylene intermediates."],"journal":["Angewandte Chemie (International ed. in English)"],"pagination":["6446-6450"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC7986239"],"repository":["biostudies-literature"],"pubmed_title":["Highly Colored Boron-Doped Thiazolothiazoles from the Reductive Dimerization of Boron Isothiocyanates."],"pmcid":["PMC7986239"],"pubmed_authors":["Vargas A","Rempel A","Braunschweig H","Fantuzzi F","Hagspiel S","Hermann A","Bruckner T","Arrowsmith M"],"additional_accession":[]},"is_claimable":false,"name":"Highly Colored Boron-Doped Thiazolothiazoles from the Reductive Dimerization of Boron Isothiocyanates.","description":"Reduction of (CAAC)BBr<sub>2</sub> (NCS) (CAAC=cyclic alkyl(amino)carbene) in the presence of a Lewis base L yields tricoordinate (CAAC)LB(NCS) borylenes which undergo reversible E/Z-isomerization. The same reduction in the absence of L yields deep blue, bis(CAAC)-stabilized, boron-doped, aromatic thiazolothiazoles resulting from the dimerization of dicoordinate (CAAC)B(NCS) borylene intermediates.","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021 Mar","modification":"2025-04-04T22:00:55.68Z","creation":"2025-04-04T22:00:55.68Z"},"accession":"S-EPMC7986239","cross_references":{"pubmed":["33492727"],"doi":["10.1002/anie.202015508"]}}