{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Ehret F"],"funding":["Ministerium für Wissenschaft, Forschung und Kunst Baden-Württemberg","Deutsche Forschungsgemeinschaft"],"pagination":["3374-3381"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC7986709"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["27(10)"],"pubmed_abstract":["Reaction of [Pt(DMSO)2 Cl2 ] or [Pd(MeCN)2 Cl2 ] with the electron-rich LH=N,N'-bis(4-dimethylaminophenyl)ethanimidamide yielded mononuclear [PtL2 ] (1) but dinuclear [Pd2 L4 ] (2), a paddle-wheel complex. The neutral compounds were characterized through experiments (crystal structures, electrochemistry, UV-vis-NIR spectroscopy, magnetic resonance) and TD-DFT calculations as metal(II) species with noninnocent ligands L- . The reversibly accessible cations [PtL2 ]+ and [Pd2 L4 ]+ were also studied, the latter as [Pd2 L4 ][B{3,5-(CF3 )2 C6 H3 }4 ] single crystals. Experimental and computational investigations were directed at the elucidation of the electronic structures, establishing the correct oxidation states within the alternatives [PtII (L- )2 ] or [Pt. (L )2 ], [PtII (L0.5- )2 ]+ or [PtIII (L- )2 ]+ , [(PdII )2 (μ-L- )4 ] or [(Pd1.5 )2 (μ-L0.75- )4 ], and [(Pd2.5 )2 (μ-L- )4 ]+ or [(PdII )2 (μ-L0.75- )4 ]+ . In each case, the first alternative was shown to be most appropriate. Remarkable results include the preference of platinum for mononuclear planar [PtL2 ] with an N-Pt-N bite angle of 62.8(2)° in contrast to [Pd2 L4 ], and the dimetal (Pd2 4+ →Pd2 5+ ) instead of ligand (L- →L ) oxidation of the dinuclear palladium compound."],"journal":["Chemistry (Weinheim an der Bergstrasse, Germany)"],"pubmed_title":["Structural and Oxidation State Alternatives in Platinum and Palladium Complexes of a Redox-Active Amidinato Ligand."],"pmcid":["PMC7986709"],"funding_grant_id":["INST 40/467-1 FUGG (Justus Cluster)","bwHPC"],"pubmed_authors":["Kaim W","Ehret F","Zalis S","Blickle S","Filippou V","Bubrin M"],"additional_accession":[]},"is_claimable":false,"name":"Structural and Oxidation State Alternatives in Platinum and Palladium Complexes of a Redox-Active Amidinato Ligand.","description":"Reaction of [Pt(DMSO)2 Cl2 ] or [Pd(MeCN)2 Cl2 ] with the electron-rich LH=N,N'-bis(4-dimethylaminophenyl)ethanimidamide yielded mononuclear [PtL2 ] (1) but dinuclear [Pd2 L4 ] (2), a paddle-wheel complex. The neutral compounds were characterized through experiments (crystal structures, electrochemistry, UV-vis-NIR spectroscopy, magnetic resonance) and TD-DFT calculations as metal(II) species with noninnocent ligands L- . The reversibly accessible cations [PtL2 ]+ and [Pd2 L4 ]+ were also studied, the latter as [Pd2 L4 ][B{3,5-(CF3 )2 C6 H3 }4 ] single crystals. Experimental and computational investigations were directed at the elucidation of the electronic structures, establishing the correct oxidation states within the alternatives [PtII (L- )2 ] or [Pt. (L )2 ], [PtII (L0.5- )2 ]+ or [PtIII (L- )2 ]+ , [(PdII )2 (μ-L- )4 ] or [(Pd1.5 )2 (μ-L0.75- )4 ], and [(Pd2.5 )2 (μ-L- )4 ]+ or [(PdII )2 (μ-L0.75- )4 ]+ . In each case, the first alternative was shown to be most appropriate. Remarkable results include the preference of platinum for mononuclear planar [PtL2 ] with an N-Pt-N bite angle of 62.8(2)° in contrast to [Pd2 L4 ], and the dimetal (Pd2 4+ →Pd2 5+ ) instead of ligand (L- →L ) oxidation of the dinuclear palladium compound.","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021 Feb","modification":"2025-04-04T14:35:10.859Z","creation":"2025-04-04T14:35:10.859Z"},"accession":"S-EPMC7986709","cross_references":{"pubmed":["32959415"],"doi":["10.1002/chem.202003636"]}}