{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Elsberg JGD"],"funding":["National Institutes of Health","NIGMS NIH HHS","National Science Foundation"],"pagination":["1712-1720"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8174646"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["50(5)"],"pubmed_abstract":["We report synthetic, structural and reactivity investigations of tris-(2-pyridylmethyl)amine (TPA)-ligated Cu(ii) 1,3-diketonate complexes. These complexes exhibit anaerobic retro-Claisen type C-C bond cleavage reactivity which exceeds that found in analogs supported by chelate ligands with fewer and/or weaker pyridyl interactions."],"journal":["Dalton transactions (Cambridge, England : 2003)"],"pubmed_title":["Tris-(2-pyridylmethyl)amine-ligated Cu(II) 1,3-diketonate complexes: anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives."],"pmcid":["PMC8174646"],"funding_grant_id":["P20 GM103546","P20GM103546","CHE-1429195","CHE-1664977","CHE-1828764"],"pubmed_authors":["Elsberg JGD","Anderson SN","Berreau LM","Tierney DL","Reinheimer EW"],"additional_accession":[]},"is_claimable":false,"name":"Tris-(2-pyridylmethyl)amine-ligated Cu(II) 1,3-diketonate complexes: anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives.","description":"We report synthetic, structural and reactivity investigations of tris-(2-pyridylmethyl)amine (TPA)-ligated Cu(ii) 1,3-diketonate complexes. These complexes exhibit anaerobic retro-Claisen type C-C bond cleavage reactivity which exceeds that found in analogs supported by chelate ligands with fewer and/or weaker pyridyl interactions.","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021 Feb","modification":"2025-04-05T10:03:37.438Z","creation":"2025-04-05T10:03:37.438Z"},"accession":"S-EPMC8174646","cross_references":{"pubmed":["33447836"],"doi":["10.1039/d0dt04074f"]}}