biostudies-literatureElsberg JGDNational Institutes of HealthNIGMS NIH HHSNational Science Foundation1712-1720https://www.ebi.ac.uk/biostudies/studies/S-EPMC8174646biostudies-literatureUnknown50(5)We report synthetic, structural and reactivity investigations of tris-(2-pyridylmethyl)amine (TPA)-ligated Cu(ii) 1,3-diketonate complexes. These complexes exhibit anaerobic retro-Claisen type C-C bond cleavage reactivity which exceeds that found in analogs supported by chelate ligands with fewer and/or weaker pyridyl interactions.Dalton transactions (Cambridge, England : 2003)Tris-(2-pyridylmethyl)amine-ligated Cu(II) 1,3-diketonate complexes: anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives.PMC8174646P20 GM103546P20GM103546CHE-1429195CHE-1664977CHE-1828764Elsberg JGDAnderson SNBerreau LMTierney DLReinheimer EWfalseTris-(2-pyridylmethyl)amine-ligated Cu(II) 1,3-diketonate complexes: anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives.We report synthetic, structural and reactivity investigations of tris-(2-pyridylmethyl)amine (TPA)-ligated Cu(ii) 1,3-diketonate complexes. These complexes exhibit anaerobic retro-Claisen type C-C bond cleavage reactivity which exceeds that found in analogs supported by chelate ligands with fewer and/or weaker pyridyl interactions.2021-01-01T00:00:00Z2021 Feb2025-04-05T10:03:37.438Z2025-04-05T10:03:37.438ZS-EPMC81746463344783610.1039/d0dt04074f