biostudies-literatureAhrens LStudienstiftung des Deutschen VolkesDeutsche Forschungsgemeinschaft9270-9273https://www.ebi.ac.uk/biostudies/studies/S-EPMC8247972biostudies-literatureUnknown60(17)A doubly alkylene bridged 6,13-diphenylpentacene and analogously bridged azapentacenes were prepared; they are persistent. The doubly bridged azapentacenes display superior photochemical, oxidative and thermal stabilities compared to azapentacenes protected by bis(TIPS-ethynyl)-substituents-clipping an azaacene into a large ring is a viable complement in stabilization.Angewandte Chemie (International ed. in English)(Aza)Pentacenes Clipped into a Ring: Stabilization of Large (Aza)Acenes.PMC8247972StipendiumSFB 1249Bunz UHFAhrens LRominger FTverskoy OWeigold SFreudenberg JGanschow Mfalse(Aza)Pentacenes Clipped into a Ring: Stabilization of Large (Aza)Acenes.A doubly alkylene bridged 6,13-diphenylpentacene and analogously bridged azapentacenes were prepared; they are persistent. The doubly bridged azapentacenes display superior photochemical, oxidative and thermal stabilities compared to azapentacenes protected by bis(TIPS-ethynyl)-substituents-clipping an azaacene into a large ring is a viable complement in stabilization.2021-01-01T00:00:00Z2021 Apr2026-05-07T20:36:39.444Z2022-02-10T17:49:47.355ZS-EPMC82479723325912310.1002/anie.202015348