{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Gomez S"],"funding":["Universidad de Antioquia","H2020 Marie Skłodowska-Curie Actions"],"pagination":["9233-9245"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8261874"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["12(26)"],"pubmed_abstract":["A thorough exploration of the molecular basis for hydrophobicity with a comprehensive set of theoretical tools and an extensive set of organic solvent S/water binary systems is discussed in this work. Without a single exception, regardless of the nature or structure of S, all quantum descriptors of bonding yield stabilizing S⋯water interactions, therefore, there is no evidence of repulsion and thus no reason for etymological hydrophobicity at the molecular level. Our results provide molecular insight behind the exclusion of S molecules by water, customarily invoked to explain phase separation and the formation of interfaces, in favor of a complex interplay between entropic, enthalpic, and dynamic factors. S⋯water interfaces are not just thin films separating the two phases; instead, they a"],"journal":["Chemical science"],"pubmed_title":["A molecular twist on hydrophobicity."],"pmcid":["PMC8261874"],"funding_grant_id":["Estrategia para la sostenibilidad","765739"],"pubmed_authors":["Rojas-Valencia N","Merino G","Cappelli C","Gomez S","Gomez SA","Restrepo A"],"additional_accession":[]},"is_claimable":false,"name":"A molecular twist on hydrophobicity.","description":"A thorough exploration of the molecular basis for hydrophobicity with a comprehensive set of theoretical tools and an extensive set of organic solvent S/water binary systems is discussed in this work. Without a single exception, regardless of the nature or structure of S, all quantum descriptors of bonding yield stabilizing S⋯water interactions, therefore, there is no evidence of repulsion and thus no reason for etymological hydrophobicity at the molecular level. Our results provide molecular insight behind the exclusion of S molecules by water, customarily invoked to explain phase separation and the formation of interfaces, in favor of a complex interplay between entropic, enthalpic, and dynamic factors. S⋯water interfaces are not just thin films separating the two phases; instead, they a","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021 Jul","modification":"2026-05-09T07:40:55.174Z","creation":"2022-02-10T20:29:39.97Z"},"accession":"S-EPMC8261874","cross_references":{"pubmed":["34276953"],"doi":["10.1039/d1sc02673a"]}}