biostudies-literatureUnknown6(27)Liu XHerein, we successfully synthesized two novel metal thiophosphites (MTPs) hybridized with carbon, that is, NiPS₃/C and SnPS₃/C composites, via an environment-friendly and cost-effective approach without harsh reaction conditions. Subsequently, the electrochemical performances of NiPS₃/C and SnPS₃/C composites have been investigated in coin-cells, and it is revealed that MTPs/C have a significantly higher Li-storage capacity and better stability compared to the MTPs without carbon. Moreover, the SnPS₃/C electrode shows a lower internal resistance and a better rate performance compared to NiPS₃/C. We employed extensive ex situ experiments to characterize the materials and interpreted the remarkably improved performance of MTPs/C.ACS omega17247-17254https://www.ebi.ac.uk/biostudies/studies/S-EPMC8280674biostudies-literatureFacile Synthesis of MPS₃/C (M = Ni and Sn) Hybrid Materials and Their Application in Lithium-Ion Batteries.PMC8280674Liu XWang MYasin GNajam TKumar MfalseFacile Synthesis of MPS₃/C (M = Ni and Sn) Hybrid Materials and Their Application in Lithium-Ion Batteries.Herein, we successfully synthesized two novel metal thiophosphites (MTPs) hybridized with carbon, that is, NiPS₃/C and SnPS₃/C composites, via an environment-friendly and cost-effective approach without harsh reaction conditions. Subsequently, the electrochemical performances of NiPS₃/C and SnPS₃/C composites have been investigated in coin-cells, and it is revealed that MTPs/C have a significantly higher Li-storage capacity and better stability compared to the MTPs without carbon. Moreover, the SnPS₃/C electrode shows a lower internal resistance and a better rate performance compared to NiPS₃/C. We employed extensive ex situ experiments to characterize the materials and interpreted the remarkably improved performance of MTPs/C.2021-01-01T00:00:00Z2021 Jul2024-02-15T09:10:01.997Z2022-02-10T20:27:11.829ZS-EPMC82806743427811110.1021/acsomega.1c01042