{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Zhou Y"],"funding":["Science and Technology Commission of Shanghai Municipality","Ministry of Education of the People&apos;s Republic of China","National Natural Science Foundation of China"],"pagination":["1141-1146"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8397364"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["1(8)"],"pubmed_abstract":["Uranyl-photocatalyzed hydrolysis of diaryl ethers has been established to achieve two types of phenols at room temperature under normal pressure. The single electron transfer process was disclosed by a radical quenching experiment and Stern-Volmer analysis between diphenyl ether and uranyl cation catalyst, followed by oxygen atom transfer process between radical cation of diphenyl ether and uranyl peroxide species. The <sup>18</sup>O-labeling experiment precisely demonstrates that the oxygen source is water. Further application in template substrates of 4-O-5 linkages from lignin and 30-fold efficiency of flow operation display the potential application for phenol recovery via an ecofriendly and low-energy consumption protocol."],"journal":["JACS Au"],"pubmed_title":["Uranyl-Photocatalyzed Hydrolysis of Diaryl Ethers at Ambient Environment for the Directional Degradation of 4-O-5 Lignin."],"pmcid":["PMC8397364"],"funding_grant_id":["20XD1421500","21971065","20JC1416800","18JC1415600"],"pubmed_authors":["Hu D","Li D","Jiang X","Zhou Y"],"additional_accession":[]},"is_claimable":false,"name":"Uranyl-Photocatalyzed Hydrolysis of Diaryl Ethers at Ambient Environment for the Directional Degradation of 4-O-5 Lignin.","description":"Uranyl-photocatalyzed hydrolysis of diaryl ethers has been established to achieve two types of phenols at room temperature under normal pressure. The single electron transfer process was disclosed by a radical quenching experiment and Stern-Volmer analysis between diphenyl ether and uranyl cation catalyst, followed by oxygen atom transfer process between radical cation of diphenyl ether and uranyl peroxide species. The <sup>18</sup>O-labeling experiment precisely demonstrates that the oxygen source is water. Further application in template substrates of 4-O-5 linkages from lignin and 30-fold efficiency of flow operation display the potential application for phenol recovery via an ecofriendly and low-energy consumption protocol.","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021 Aug","modification":"2026-05-09T07:09:02.95Z","creation":"2022-02-11T10:12:13.034Z"},"accession":"S-EPMC8397364","cross_references":{"pubmed":["34467354"],"doi":["10.1021/jacsau.1c00168"]}}