biostudies-literatureRodriguez-Barea BMinisterio de Ciencia, Innovaci??n y UniversidadesMinisterio de Econom??a y CompetitividadGeneralitat Valenciana12719-12723https://www.ebi.ac.uk/biostudies/studies/S-EPMC8424628biostudies-literatureUnknown60(17)The coexistence of field-induced blockage of the magnetization and significant magnetocaloric effects in the low-temperature region occurs in a mononuclear holmium(III) diethylenetriamine-<i>N</i>,<i>N</i>,<i>N</i>',<i>N</i>″,<i>N</i>″-pentaacetate complex, whose gadolinium(III) analogue is a commercial MRI contrast agent. Both properties make it a suitable candidate for cryogenic magnetic refrigeration, thus enlarging the variety of applications of this simple class of multifunctional molecular nanomagnets.Inorganic chemistryHolmium(III) Single-Ion Magnet for Cryomagnetic Refrigeration Based on an MRI Contrast Agent Derivative.PMC8424628AICO/2020/183CEX2019-000919-MGRISOLIA/2017/057PID2019- 109735GB-I00FPU/2017/02638Mayans JJulve MMartinez-Lillo JLloret FRodriguez-Barea BRuiz-Garcia RCano JSanchis-Perucho AMoliner NRabelo RfalseHolmium(III) Single-Ion Magnet for Cryomagnetic Refrigeration Based on an MRI Contrast Agent Derivative.The coexistence of field-induced blockage of the magnetization and significant magnetocaloric effects in the low-temperature region occurs in a mononuclear holmium(III) diethylenetriamine-<i>N</i>,<i>N</i>,<i>N</i>',<i>N</i>″,<i>N</i>″-pentaacetate complex, whose gadolinium(III) analogue is a commercial MRI contrast agent. Both properties make it a suitable candidate for cryogenic magnetic refrigeration, thus enlarging the variety of applications of this simple class of multifunctional molecular nanomagnets.2021-01-01T00:00:00Z2021 Sep2024-11-08T11:17:39.251Z2022-02-11T10:47:52.618ZS-EPMC84246283442468010.1021/acs.inorgchem.1c01905