{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["17"],"submitter":["Kocaarslan A"],"pubmed_abstract":["The development of long-wavelength photoinduced copper-catalyzed azide-alkyne click (CuAAC) reaction routes is attractive for organic and polymer chemistry. In this study, we present a novel synthetic methodology for the photoinduced CuAAC reaction utilizing exfoliated two-dimensional (2D) few-layer black phosphorus nanosheets (BPNs) as photocatalysts under white LED and near-IR (NIR) light irradiation. Upon irradiation, BPNs generated excited electrons and holes on its conduction (CB) and valence band (VB), respectively. The excited electrons thus formed were then transferred to the Cu<sup>II</sup> ions to produce active Cu<sup>I</sup> catalysts. The ability of BPNs to initiate the CuAAC reaction was investigated by studying the reaction between various low molar mass alkyne and azide der"],"journal":["Beilstein journal of organic chemistry"],"pagination":["2477-2487"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8474068"],"repository":["biostudies-literature"],"pubmed_title":["Exfoliated black phosphorous-mediated CuAAC chemistry for organic and macromolecular synthesis under white LED and near-IR irradiation."],"pmcid":["PMC8474068"],"pubmed_authors":["Yagci Y","Kocaarslan A","Eroglu Z","Metin O"],"additional_accession":[]},"is_claimable":false,"name":"Exfoliated black phosphorous-mediated CuAAC chemistry for organic and macromolecular synthesis under white LED and near-IR irradiation.","description":"The development of long-wavelength photoinduced copper-catalyzed azide-alkyne click (CuAAC) reaction routes is attractive for organic and polymer chemistry. In this study, we present a novel synthetic methodology for the photoinduced CuAAC reaction utilizing exfoliated two-dimensional (2D) few-layer black phosphorus nanosheets (BPNs) as photocatalysts under white LED and near-IR (NIR) light irradiation. Upon irradiation, BPNs generated excited electrons and holes on its conduction (CB) and valence band (VB), respectively. The excited electrons thus formed were then transferred to the Cu<sup>II</sup> ions to produce active Cu<sup>I</sup> catalysts. The ability of BPNs to initiate the CuAAC reaction was investigated by studying the reaction between various low molar mass alkyne and azide der","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021","modification":"2025-04-21T14:52:38.979Z","creation":"2022-02-11T12:02:08.248Z"},"accession":"S-EPMC8474068","cross_references":{"pubmed":["34630727"],"doi":["10.3762/bjoc.17.164"]}}