{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Yang L"],"funding":["Deutsche Forschungsgemeinschaft"],"pagination":["12971-12976"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8513870"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["12(39)"],"pubmed_abstract":["Copper-catalyzed electrochemical direct chalcogenations of <i>o</i>-carboranes was established at room temperature. Thereby, a series of cage C-sulfenylated and C-selenylated <i>o</i>-carboranes anchored with valuable functional groups was accessed with high levels of position- and chemo-selectivity control. The cupraelectrocatalysis provided efficient means to activate otherwise inert cage C-H bonds for the late-stage diversification of <i>o</i>-carboranes."],"journal":["Chemical science"],"pubmed_title":["Electrooxidative <i>o</i>-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature."],"pmcid":["PMC8513870"],"funding_grant_id":["Gottfried-Wilhelm-Leibniz prize"],"pubmed_authors":["Yang L","Jei BB","Stuckl AC","Yuan B","Scheremetjew A","Ackermann L"],"additional_accession":[]},"is_claimable":false,"name":"Electrooxidative <i>o</i>-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature.","description":"Copper-catalyzed electrochemical direct chalcogenations of <i>o</i>-carboranes was established at room temperature. Thereby, a series of cage C-sulfenylated and C-selenylated <i>o</i>-carboranes anchored with valuable functional groups was accessed with high levels of position- and chemo-selectivity control. The cupraelectrocatalysis provided efficient means to activate otherwise inert cage C-H bonds for the late-stage diversification of <i>o</i>-carboranes.","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021 Oct","modification":"2025-06-01T00:56:50.18Z","creation":"2025-06-01T00:56:50.18Z"},"accession":"S-EPMC8513870","cross_references":{"pubmed":["34745527"],"doi":["10.1039/d1sc02905c"]}}