{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Han G"],"funding":["University of Liverpool","The Faraday Institution","Faraday Institution","Engineering and Physical Sciences Research Council"],"pagination":["18216-18232"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8569803"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["143(43)"],"pubmed_abstract":["Extended anionic frameworks based on condensation of polyhedral main group non-metal anions offer a wide range of structure types. Despite the widespread chemistry and earth abundance of phosphates and silicates, there are no reports of extended ultraphosphate anions with lithium. We describe the lithium ultraphosphates Li<sub>3</sub>P<sub>5</sub>O<sub>14</sub> and Li<sub>4</sub>P<sub>6</sub>O<sub>17</sub> based on extended layers and chains of phosphate, respectively. Li<sub>3</sub>P<sub>5</sub>O<sub>14</sub> presents a complex structure containing infinite ultraphosphate layers with 12-membered rings that are stacked alternately with lithium polyhedral layers. Two distinct vacant tetrahedral sites were identified at the end of two distinct finite Li<sub>6</sub>O<sub>16</sub><sup>26-</sup"],"journal":["Journal of the American Chemical Society"],"pubmed_title":["Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability."],"pmcid":["PMC8569803"],"funding_grant_id":["EP/N004884/1","FIRG007","EP/S019367/1","FIRG026","EP/N004884","EP/R008280/1","EP/R00661X/1"],"pubmed_authors":["Kershaw Cook LJ","Dyer MS","Blanc F","Vasylenko A","Robertson CM","Daniels LM","Hardwick LJ","Claridge JB","Rosseinsky MJ","Duff BB","Han G","Knapp M","Neale AR","Hansen AL","Dang Y","Zanella M","Chen R"],"additional_accession":[]},"is_claimable":false,"name":"Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability.","description":"Extended anionic frameworks based on condensation of polyhedral main group non-metal anions offer a wide range of structure types. Despite the widespread chemistry and earth abundance of phosphates and silicates, there are no reports of extended ultraphosphate anions with lithium. We describe the lithium ultraphosphates Li<sub>3</sub>P<sub>5</sub>O<sub>14</sub> and Li<sub>4</sub>P<sub>6</sub>O<sub>17</sub> based on extended layers and chains of phosphate, respectively. Li<sub>3</sub>P<sub>5</sub>O<sub>14</sub> presents a complex structure containing infinite ultraphosphate layers with 12-membered rings that are stacked alternately with lithium polyhedral layers. Two distinct vacant tetrahedral sites were identified at the end of two distinct finite Li<sub>6</sub>O<sub>16</sub><sup>26-</sup","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021 Nov","modification":"2026-05-08T07:09:51.265Z","creation":"2026-04-07T23:40:41.907Z"},"accession":"S-EPMC8569803","cross_references":{"pubmed":["34677973"],"doi":["10.1021/jacs.1c07874"]}}