{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["11(2)"],"submitter":["Kim SJ"],"pubmed_abstract":["The synthesis of organic-inorganic hybrid materials using individual metal-organic molecules as building blocks has been of interest for the last few decades. These hybrid materials are appealing due to the opportunities they provide with respect to a variety of potential applications. Here, we report a novel metal-organic nanostructure made by a hybrid synthetic process that is comprised of thermal evaporation (TE) and atomic layer deposition (ALD) for the metalation of an organic layer. In this work, 5,10,15,20-tetrakis(4-hydroxyphenyl)-21<i>H</i>,23<i>H</i>-porphyrin (<i>p</i>-(H<sub>6</sub>)THPP) and tin(ii) bis(trimethylsilyl)amide (Sn(btsa)<sub>2</sub>) (or diethylzinc (DEZ)) were utilized as the main organic layer and ALD precursors, respectively. Sn and Zn atoms were coordinated sequentially <i>via</i> surface chemical reactions on specific functional groups of the <i>p</i>-(H<sub>6</sub>)THPP layer, which was deposited on a solid substrate. X-ray photoelectron spectroscopy (XPS) and UV-vis absorption spectroscopy were used to characterize and confirm the growth mechanism and optical properties of the synthesized hybrid films. This method should serve as a major breakthrough for building advanced organic-inorganic materials-based devices."],"journal":["RSC advances"],"pagination":["830-837"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8693389"],"repository":["biostudies-literature"],"pubmed_title":["Selective coordination with heterogeneous metal atoms for inorganic-organic hybrid layers."],"pmcid":["PMC8693389"],"pubmed_authors":["Jeon IS","Lim J","Lee SS","Myung S","Chung TM","Kim SJ","Song W","An KS"],"additional_accession":[]},"is_claimable":false,"name":"Selective coordination with heterogeneous metal atoms for inorganic-organic hybrid layers.","description":"The synthesis of organic-inorganic hybrid materials using individual metal-organic molecules as building blocks has been of interest for the last few decades. These hybrid materials are appealing due to the opportunities they provide with respect to a variety of potential applications. Here, we report a novel metal-organic nanostructure made by a hybrid synthetic process that is comprised of thermal evaporation (TE) and atomic layer deposition (ALD) for the metalation of an organic layer. In this work, 5,10,15,20-tetrakis(4-hydroxyphenyl)-21<i>H</i>,23<i>H</i>-porphyrin (<i>p</i>-(H<sub>6</sub>)THPP) and tin(ii) bis(trimethylsilyl)amide (Sn(btsa)<sub>2</sub>) (or diethylzinc (DEZ)) were utilized as the main organic layer and ALD precursors, respectively. Sn and Zn atoms were coordinated sequentially <i>via</i> surface chemical reactions on specific functional groups of the <i>p</i>-(H<sub>6</sub>)THPP layer, which was deposited on a solid substrate. X-ray photoelectron spectroscopy (XPS) and UV-vis absorption spectroscopy were used to characterize and confirm the growth mechanism and optical properties of the synthesized hybrid films. This method should serve as a major breakthrough for building advanced organic-inorganic materials-based devices.","dates":{"release":"2020-01-01T00:00:00Z","publication":"2020 Dec","modification":"2025-04-05T13:07:58.303Z","creation":"2025-04-05T13:07:58.303Z"},"accession":"S-EPMC8693389","cross_references":{"pubmed":["35423685"],"doi":["10.1039/d0ra09415c"]}}