{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["11(4)"],"submitter":["Li Y"],"pubmed_abstract":["The luminescence of dielectric phase transition materials is one important property for technological applications, such as low-energy electron excitation. The combination of dielectric phase transitions and luminescence within organic-inorganic hybrids would lead to a new type of luminescent dielectric phase transition multifunctional material. Here, we report two novel A<sub>2</sub>BX<sub>4</sub> organic-inorganic hybrid complexes [Me<sub>3</sub>NVinyl]<sub>2</sub>[MnCl<sub>4</sub>] 1 and [Me<sub>3</sub>NVinyl]<sub>2</sub>[MnBr<sub>4</sub>] 2, ([Me<sub>3</sub>NVinyl] = trimethylvinyl ammonium cation). The complexes 1 and 2 were found to undergo continuous reversible phase transitions as well as switch dielectric phase transitions. Strikingly, intensive red luminescence and green luminesc"],"journal":["RSC advances"],"pagination":["2329-2336"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8693754"],"repository":["biostudies-literature"],"pubmed_title":["Red/green-light emission in continuous dielectric phase transition materials: [Me<sub>3</sub>NVinyl]<sub>2</sub>[MnX<sub>4</sub>] (X = Cl, Br)."],"pmcid":["PMC8693754"],"pubmed_authors":["Li H","Li Y","Yang J","Jiang T","Lin L","Qian K"],"additional_accession":[]},"is_claimable":false,"name":"Red/green-light emission in continuous dielectric phase transition materials: [Me<sub>3</sub>NVinyl]<sub>2</sub>[MnX<sub>4</sub>] (X = Cl, Br).","description":"The luminescence of dielectric phase transition materials is one important property for technological applications, such as low-energy electron excitation. The combination of dielectric phase transitions and luminescence within organic-inorganic hybrids would lead to a new type of luminescent dielectric phase transition multifunctional material. Here, we report two novel A<sub>2</sub>BX<sub>4</sub> organic-inorganic hybrid complexes [Me<sub>3</sub>NVinyl]<sub>2</sub>[MnCl<sub>4</sub>] 1 and [Me<sub>3</sub>NVinyl]<sub>2</sub>[MnBr<sub>4</sub>] 2, ([Me<sub>3</sub>NVinyl] = trimethylvinyl ammonium cation). The complexes 1 and 2 were found to undergo continuous reversible phase transitions as well as switch dielectric phase transitions. Strikingly, intensive red luminescence and green luminesc","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021 Jan","modification":"2025-04-25T22:59:30.981Z","creation":"2025-04-06T09:12:54.287Z"},"accession":"S-EPMC8693754","cross_references":{"pubmed":["35424178"],"doi":["10.1039/d0ra08795e"]}}