{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["11(8)"],"submitter":["Tent JA"],"pubmed_abstract":["In this report, syntheses and subsequent electropolymerization of a series of five rigid tricarbazole monomers are described. The monomers involve three planar triphenylene-cored tricarbazole-benzenes (with the carbazole units connected <i>via</i> their <i>a</i>- or <i>b</i>-planes) and two triptycene-cored derivatives. Oxidative electropolymerization of these monomers leads to a continuous growth of smooth and freestanding thin films. Moreover, one type of polymer film, based on a poly-<i>a</i>-tricarbazole network (paTC), shows the occurrence of intrinsic microporosity properties, with a specific BET surface area of 260 m<sup>2</sup> g<sup>-1</sup>."],"journal":["RSC advances"],"pagination":["4654-4659"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8694549"],"repository":["biostudies-literature"],"pubmed_title":["Electrooxidative generation of polymer films from rigid tricarbazole monomers."],"pmcid":["PMC8694549"],"pubmed_authors":["Scherf U","Braun M","Tent JA","Ammenhauser R"],"additional_accession":[]},"is_claimable":false,"name":"Electrooxidative generation of polymer films from rigid tricarbazole monomers.","description":"In this report, syntheses and subsequent electropolymerization of a series of five rigid tricarbazole monomers are described. The monomers involve three planar triphenylene-cored tricarbazole-benzenes (with the carbazole units connected <i>via</i> their <i>a</i>- or <i>b</i>-planes) and two triptycene-cored derivatives. Oxidative electropolymerization of these monomers leads to a continuous growth of smooth and freestanding thin films. Moreover, one type of polymer film, based on a poly-<i>a</i>-tricarbazole network (paTC), shows the occurrence of intrinsic microporosity properties, with a specific BET surface area of 260 m<sup>2</sup> g<sup>-1</sup>.","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021 Jan","modification":"2025-04-04T19:57:58.106Z","creation":"2025-04-04T19:57:58.106Z"},"accession":"S-EPMC8694549","cross_references":{"pubmed":["35424403"],"doi":["10.1039/d0ra09988k"]}}