{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Mougharbel AS"],"funding":["Jacobs University","Deutsche Forschungsgemeinschaft","European Cooperation in Science and Technology"],"pagination":["34494-34500"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8697379"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["6(50)"],"pubmed_abstract":["The synthesis of four organometallic RhCp*- and IrCp*-containing heteropoly-20-tungstates, [{RhCp*}2Bi2W20O70]10- (1), [{IrCp*}2Bi2W20O70]10- (2), [{RhCp*}2Sb2W20O70]10- (3), and [{IrCp*}2Sb2W20O70]10- (4) has been accomplished by reaction of (MCp*Cl2)2 with [X2W22O74(OH)2]12- in aqueous solution at pH 6 and 70 °C. The four polyanions 1-4 were structurally characterized in the solid state by single-crystal XRD, FTIR, and TGA and in solution by 1832X2W20O70]10- (M = RhIII and IrIII; X = BiIII and SbIII)."],"pmcid":["PMC8697379"],"funding_grant_id":["CM1203","KO 2288/20-1"],"pubmed_authors":["Rajan A","Kortz U","Ahmedi S","Bhattacharya S","Mougharbel AS"],"additional_accession":[]},"is_claimable":false,"name":"Organorhodium(III)- and Iridium(III)-Substituted 20-Tungstobismuthates(III) and -Antimonates(III), [(MCp*)2X2W20O70]10- (M = RhIII and IrIII; X = BiIII and SbIII).","description":"The synthesis of four organometallic RhCp*- and IrCp*-containing heteropoly-20-tungstates, [{RhCp*}2Bi2W20O70]10- (1), [{IrCp*}2Bi2W20O70]10- (2), [{RhCp*}2Sb2W20O70]10- (3), and [{IrCp*}2Sb2W20O70]10- (4) has been accomplished by reaction of (MCp*Cl2)2 with [X2W22O74(OH)2]12- in aqueous solution at pH 6 and 70 °C. The four polyanions 1-4 were structurally characterized in the solid state by single-crystal XRD, FTIR, and TGA and in solution by 183