{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Abe K"],"funding":["Japan Society for the Promotion of Science"],"pagination":["15296-15300"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8698244"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["11(25)"],"pubmed_abstract":["Three cubic crystalline icosahedral approximants (C phase: Al<sub>72.0</sub>Pd<sub>16.4</sub>Fe<sub>11.6</sub>, P<sub>40</sub> phase: Al<sub>72.0</sub>Pd<sub>16.4</sub>Ru<sub>11.6</sub>, P<sub>20</sub> phase: Al<sub>70.0</sub>Pd<sub>22.3</sub>Ru<sub>7.7</sub>) exhibit high ethylene selectivity of over 90% for hydrogenating acetylene at 150 °C. Moreover, the powdered P<sub>20</sub> also demonstrates a high catalytic performance under an industry-like ethylene feed containing 0.5% acetylene as an impurity. Overall, icosahedral approximants in the Al-Pd-(Ru, Fe) systems are promising as a novel class of alloy catalysts."],"journal":["RSC advances"],"pubmed_title":["High catalytic performance of Al-Pd-(Ru, Fe) icosahedral approximants for acetylene semi-hydrogenation."],"pmcid":["PMC8698244"],"funding_grant_id":["JP19H05819","JP19H05821"],"pubmed_authors":["Fujita N","Tsukuda R","Kameoka S","Abe K"],"additional_accession":[]},"is_claimable":false,"name":"High catalytic performance of Al-Pd-(Ru, Fe) icosahedral approximants for acetylene semi-hydrogenation.","description":"Three cubic crystalline icosahedral approximants (C phase: Al<sub>72.0</sub>Pd<sub>16.4</sub>Fe<sub>11.6</sub>, P<sub>40</sub> phase: Al<sub>72.0</sub>Pd<sub>16.4</sub>Ru<sub>11.6</sub>, P<sub>20</sub> phase: Al<sub>70.0</sub>Pd<sub>22.3</sub>Ru<sub>7.7</sub>) exhibit high ethylene selectivity of over 90% for hydrogenating acetylene at 150 °C. Moreover, the powdered P<sub>20</sub> also demonstrates a high catalytic performance under an industry-like ethylene feed containing 0.5% acetylene as an impurity. Overall, icosahedral approximants in the Al-Pd-(Ru, Fe) systems are promising as a novel class of alloy catalysts.","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021 Apr","modification":"2025-04-22T22:00:51.601Z","creation":"2025-04-06T03:55:29.16Z"},"accession":"S-EPMC8698244","cross_references":{"pubmed":["35424072"],"doi":["10.1039/d1ra01958a"]}}