{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Ghosh S"],"funding":["Ben-Gurion University of the Negev","Israel Science Foundation"],"pagination":["581-589"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8762645"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["14(1)"],"pubmed_abstract":["Bifunctional electrocatalysts for efficient hydrogen generation from water splitting must overcome both the sluggish water dissociation step of the alkaline hydrogen evolution half-reaction (HER) and the kinetic barrier of the anodic oxygen evolution half-reaction (OER). Nickel phosphides are a promising catalysts family and are known to develop a thin active layer of oxidized Ni in an alkaline medium. Here, Ni<sub>12</sub>P<sub>5</sub> was recognized as a suitable platform for the electrochemical production of γ-NiOOH─a particularly active phase─because of its matching crystallographic structure. The incorporation of tungsten by doping produces additional surface roughness, increases the electrochemical surface area (ESCA), and reduces the energy barrier for electron-coupled water dissoci"],"journal":["ACS applied materials & interfaces"],"pubmed_title":["W Doping in Ni<sub>12</sub>P<sub>5</sub> as a Platform to Enhance Overall Electrochemical Water Splitting."],"pmcid":["PMC8762645"],"funding_grant_id":["1212/21"],"pubmed_authors":["Neyman A","Ghosh S","Bar-Ziv R","Bar-Sadan M","Kadam SR","Kolatkar S","Singh C","Enyashin AN"],"additional_accession":[]},"is_claimable":false,"name":"W Doping in Ni<sub>12</sub>P<sub>5</sub> as a Platform to Enhance Overall Electrochemical Water Splitting.","description":"Bifunctional electrocatalysts for efficient hydrogen generation from water splitting must overcome both the sluggish water dissociation step of the alkaline hydrogen evolution half-reaction (HER) and the kinetic barrier of the anodic oxygen evolution half-reaction (OER). Nickel phosphides are a promising catalysts family and are known to develop a thin active layer of oxidized Ni in an alkaline medium. Here, Ni<sub>12</sub>P<sub>5</sub> was recognized as a suitable platform for the electrochemical production of γ-NiOOH─a particularly active phase─because of its matching crystallographic structure. The incorporation of tungsten by doping produces additional surface roughness, increases the electrochemical surface area (ESCA), and reduces the energy barrier for electron-coupled water dissoci","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Jan","modification":"2025-05-29T21:12:25.025Z","creation":"2025-05-29T21:12:25.025Z"},"accession":"S-EPMC8762645","cross_references":{"pubmed":["34963045"],"doi":["10.1021/acsami.1c16755"]}}