{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Matsumoto K"],"funding":["MEXT | Japan Society for the Promotion of Science","MEXT | Japan Society for the Promotion of Science (JSPS)"],"pagination":["1047"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8873263"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["13(1)"],"pubmed_abstract":["An infinite number of crystal structures in a multicomponent alloy with a specific atomic ratio can be devised, although only thermodynamically-stable phases can be formed. Here, we experimentally show the first example of a layer-structured pseudo-binary alloy, theoretically called Z3-FePd<sub>3</sub>. This Z3 structure is achieved by adding a small amount of In, which is immiscible with Fe but miscible with Pd and consists of an alternate L1<sub>0</sub> (CuAu-type)-PdFePd trilayer and Pd-In ordered alloy monolayer along the c axis. First-principles calculations strongly support that the specific inter-element miscibility of In atoms stabilizes the thermodynamically-unstable Z3-FePd<sub>3</sub> phase without significantly changing the original density of states of the Z3-FePd<sub>3</sub> phase. Our results demonstrate that the specific inter-element miscibility can switch stable structures and manipulate the material nature with a slight composition change."],"journal":["Nature communications"],"pubmed_title":["Inter-element miscibility driven stabilization of ordered pseudo-binary alloy."],"pmcid":["PMC8873263"],"funding_grant_id":["JP16H03826","JP19H05634"],"pubmed_authors":["Inagaki Y","Auchi M","Teranishi T","Yamauchi M","Kurata H","Yamazoe S","Sato R","Haruta M","Matsumoto K","Kudo M","Tatetsu Y","Horibe Y","Takahata R","Toriyama T"],"additional_accession":[]},"is_claimable":false,"name":"Inter-element miscibility driven stabilization of ordered pseudo-binary alloy.","description":"An infinite number of crystal structures in a multicomponent alloy with a specific atomic ratio can be devised, although only thermodynamically-stable phases can be formed. Here, we experimentally show the first example of a layer-structured pseudo-binary alloy, theoretically called Z3-FePd<sub>3</sub>. This Z3 structure is achieved by adding a small amount of In, which is immiscible with Fe but miscible with Pd and consists of an alternate L1<sub>0</sub> (CuAu-type)-PdFePd trilayer and Pd-In ordered alloy monolayer along the c axis. First-principles calculations strongly support that the specific inter-element miscibility of In atoms stabilizes the thermodynamically-unstable Z3-FePd<sub>3</sub> phase without significantly changing the original density of states of the Z3-FePd<sub>3</sub> phase. Our results demonstrate that the specific inter-element miscibility can switch stable structures and manipulate the material nature with a slight composition change.","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Feb","modification":"2025-04-25T22:59:17.527Z","creation":"2025-04-06T09:11:48.418Z"},"accession":"S-EPMC8873263","cross_references":{"pubmed":["35210441"],"doi":["10.1038/s41467-022-28710-0"]}}