{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Blanco AA"],"funding":["National Science Foundation"],"pagination":["1213"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8874602"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["27(4)"],"pubmed_abstract":["Compounds that exhibit spin-crossover (SCO) type behavior have been extensively investigated due to their ability to act as molecular switches. Depending on the coordinating ligand, in this case 1H-1,2,4-triazole, and the crystallite size of the SCO compound produced, the energy requirement for the spin state transition can vary. Here, SCO [Fe(Htrz)2(trz)](BF4)] nanoparticles were synthesized using modified reverse micelle methods. Reaction conditions and reagent ratios are strictly controlled to produce nanocubes of 40-50 nm in size. Decreases in energy requirements are seen in both thermal and magnetic transitions for the smaller sized crystallites, where, compared to bulk materials, a decrease of as much as 20 °C can be seen in low to high spin state transitions."],"journal":["Molecules (Basel, Switzerland)"],"pubmed_title":["Synthesis and Characterization of [Fe(Htrz)2(trz)](BF4)] Nanocubes."],"pmcid":["PMC8874602"],"funding_grant_id":["CHE-2004178","OIA-1757220","ECCS-1546650"],"pubmed_authors":["Spinu L","Azoulay JD","Adams DJ","Blanco AA","Wiley JB"],"additional_accession":[]},"is_claimable":false,"name":"Synthesis and Characterization of [Fe(Htrz)2(trz)](BF4)] Nanocubes.","description":"Compounds that exhibit spin-crossover (SCO) type behavior have been extensively investigated due to their ability to act as molecular switches. Depending on the coordinating ligand, in this case 1H-1,2,4-triazole, and the crystallite size of the SCO compound produced, the energy requirement for the spin state transition can vary. Here, SCO [Fe(Htrz)2(trz)](BF4)] nanoparticles were synthesized using modified reverse micelle methods. Reaction conditions and reagent ratios are strictly controlled to produce nanocubes of 40-50 nm in size. Decreases in energy requirements are seen in both thermal and magnetic transitions for the smaller sized crystallites, where, compared to bulk materials, a decrease of as much as 20 °C can be seen in low to high spin state transitions.","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Feb","modification":"2025-04-22T01:47:09.54Z","creation":"2025-04-05T20:06:22.945Z"},"accession":"S-EPMC8874602","cross_references":{"pubmed":["35209000"],"doi":["10.3390/molecules27041213"]}}