biostudies-literatureHu HNational Natural Science Foundation of Chinae202100296https://www.ebi.ac.uk/biostudies/studies/S-EPMC8889508biostudies-literatureUnknown11(3)Selenium (Se) is an element in the same main group as sulfur and is characterized by high electrical conductivity and large capacity (675 mAh g^-1 ). Herein, a novel ultra-high dispersion amorphous selenium graphene composite (a-Se/rGO) was synthesized and a selenium nanorods graphene composite (b-Se/rGO) was prepared by hydrothermal method as the cathode material for all solid-state lithium-selenium (Li-Se) batteries, hoping to improve the efficiency and utilization rate of active substances in all solid-state batteries. The all-solid-state batteries were assembled using a heated thawing electrolyte (2LiIHPN-LiI; HPN=3-hydroxypropionitrile). The utilization rate of a-Se/rGO was 103 % and the capacity was 697 mAh g^-1 , which remained at 281 mAh g^-1 (41.6 % oChemistryOpenAmorphous Selenium and Crystalline Selenium Nanorods Graphene Composites as Cathode Materials for All-Solid-State Lithium Selenium Batteries.PMC88895082170031075Shen ZHu HFu ZYan RLiu FfalseAmorphous Selenium and Crystalline Selenium Nanorods Graphene Composites as Cathode Materials for All-Solid-State Lithium Selenium Batteries.Selenium (Se) is an element in the same main group as sulfur and is characterized by high electrical conductivity and large capacity (675 mAh g^-1 ). Herein, a novel ultra-high dispersion amorphous selenium graphene composite (a-Se/rGO) was synthesized and a selenium nanorods graphene composite (b-Se/rGO) was prepared by hydrothermal method as the cathode material for all solid-state lithium-selenium (Li-Se) batteries, hoping to improve the efficiency and utilization rate of active substances in all solid-state batteries. The all-solid-state batteries were assembled using a heated thawing electrolyte (2LiIHPN-LiI; HPN=3-hydroxypropionitrile). The utilization rate of a-Se/rGO was 103 % and the capacity was 697 mAh g^-1 , which remained at 281 mAh g^-1 (41.6 % o2022-01-01T00:00:00Z2022 Mar2025-04-25T22:26:54.592Z2025-04-06T09:02:55.974ZS-EPMC88895083519496010.1002/open.202100296