{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Vemuri PY"],"funding":["European Research Council","Deutsche Forschungsgemeinschaft"],"pagination":["1626-1630"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8902801"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["24(8)"],"pubmed_abstract":["Oxidative clicklike reactions are useful for the late-stage functionalization of pharmaceuticals and organic materials. Hence, novel methodologies that enable such transformations are in high demand. Herein we describe a tellurium(II)-catalyzed cross-dehydrogenative phenothiazination (CDP) of aromatic amines. A key feature of this method is a cooperative effect between the phenotellurazine catalyst and the silver salt, which serves as a chemical oxidant for the reaction. This novel catalysis concept therefore enables a considerably broader scope compared with previous chemical oxidation methods."],"journal":["Organic letters"],"pubmed_title":["Te(II)-Catalyzed Cross-Dehydrogenative Phenothiazination of Anilines."],"pmcid":["PMC8902801"],"funding_grant_id":["SFB/TRR 88","716136"],"pubmed_authors":["Vemuri PY","Cremer C","Patureau FW"],"additional_accession":[]},"is_claimable":false,"name":"Te(II)-Catalyzed Cross-Dehydrogenative Phenothiazination of Anilines.","description":"Oxidative clicklike reactions are useful for the late-stage functionalization of pharmaceuticals and organic materials. Hence, novel methodologies that enable such transformations are in high demand. Herein we describe a tellurium(II)-catalyzed cross-dehydrogenative phenothiazination (CDP) of aromatic amines. A key feature of this method is a cooperative effect between the phenotellurazine catalyst and the silver salt, which serves as a chemical oxidant for the reaction. This novel catalysis concept therefore enables a considerably broader scope compared with previous chemical oxidation methods.","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Mar","modification":"2025-04-26T04:37:08.982Z","creation":"2025-04-06T11:12:50.128Z"},"accession":"S-EPMC8902801","cross_references":{"pubmed":["35192766"],"doi":["10.1021/acs.orglett.2c00125"]}}