{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Sales Monteiro MK"],"funding":["Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico","Agencia Estatal de Investigaci?n","European Regional Development Fund"],"pagination":["3263-3271"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8919508"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["61(9)"],"pubmed_abstract":["This work focuses on the electrochemical production of hydrogen peroxide in supporting electrolytes containing perchlorate ions for being used as a reagent in the reduction of chlorates to produce chlorine dioxide, as a first step in the manufacture of portable ClO<sub>2</sub> production devices. This study evaluates the effect of the current density, pressure, and temperature on the production of hydrogen peroxide, and concentrations over 400 mg L<sup>-1</sup> are reached. The average rate for the formation of hydrogen peroxide is 9.85 mg h<sup>-1</sup>, and the effect of increasing electrolyte concentration (3.0 and 30.0 g L<sup>-1</sup> perchloric acid), intensity, and pressure results in values of, respectively, -2.99, -4.49, and +7.73 mg h<sup>-1</sup>. During the manufacturing proces"],"journal":["Industrial & engineering chemistry research"],"pubmed_title":["Electrochemical Production of Hydrogen Peroxide in Perchloric Acid Supporting Electrolytes for the Synthesis of Chlorine Dioxide."],"pmcid":["PMC8919508"],"funding_grant_id":["202069/2019-2","PID2019-110904RB-I00","PID2019-107271RB-I00"],"pubmed_authors":["Dos Santos EV","Sales Monteiro MK","Rodrigo MA","Moratalla A","Saez C"],"additional_accession":[]},"is_claimable":false,"name":"Electrochemical Production of Hydrogen Peroxide in Perchloric Acid Supporting Electrolytes for the Synthesis of Chlorine Dioxide.","description":"This work focuses on the electrochemical production of hydrogen peroxide in supporting electrolytes containing perchlorate ions for being used as a reagent in the reduction of chlorates to produce chlorine dioxide, as a first step in the manufacture of portable ClO<sub>2</sub> production devices. This study evaluates the effect of the current density, pressure, and temperature on the production of hydrogen peroxide, and concentrations over 400 mg L<sup>-1</sup> are reached. The average rate for the formation of hydrogen peroxide is 9.85 mg h<sup>-1</sup>, and the effect of increasing electrolyte concentration (3.0 and 30.0 g L<sup>-1</sup> perchloric acid), intensity, and pressure results in values of, respectively, -2.99, -4.49, and +7.73 mg h<sup>-1</sup>. During the manufacturing proces","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Mar","modification":"2025-04-29T11:00:34.355Z","creation":"2025-04-06T19:50:16.337Z"},"accession":"S-EPMC8919508","cross_references":{"pubmed":["35300272"],"doi":["10.1021/acs.iecr.1c04845"]}}