biostudies-literatureRashed AEAcademy of Scientific Research and TechnologyMinistry of Higher Education8403-8419https://www.ebi.ac.uk/biostudies/studies/S-EPMC8928532biostudies-literatureUnknown7(10)The design of a highly active Fe-supported catalyst with the optimum particle and pore size, dispersion, loading, and stability is essential for obtaining the desired product selectivity. This study employed a solvothermal method to prepare two Fe-MIL-88B metal-organic framework (MOF)-derived catalysts using triethylamine (TEA) or NaOH as deprotonation catalysts. The catalysts were analyzed using X-ray diffraction, N₂-physisorption, Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, H₂ temperature-programed reduction, and thermogravimetric analysis and were evaluated for the Fischer-Tropsch synthesis performance. It was evident that the catalyst preparation in the presence of TEA produces a higher MOF yield and smaller crystal size than those produced using NaOH. The pyrolysis of MOFs yielded catalysts with different Fe particle sizes of 6 and 35 nm for the preparation in the presence of TEA and NaOH, respectively. Also, both types of catalysts exhibited a high Fe loading (50%) and good stability after 100 h reaction time. The smaller particle size TEA catalyst showed higher activity and higher olefin yield, with 94% CO conversion and a higher olefin yield of 24% at a lower reaction temperature of 280 °C and 20 bar at H₂/CO = 1. Moreover, the smaller particle size TEA catalyst exhibited higher Fe time yield and CH₄ selectivity but with lower chain growth probability (α) and C₅₊ selectivity.ACS omegaFe Nanoparticle Size Control of the Fe-MOF-Derived Catalyst Using a Solvothermal Method: Effect on FTS Activity and Olefin Production.PMC89285327825El-Moneim AANasser AElkady MFRashed AEMatsushita YfalseFe Nanoparticle Size Control of the Fe-MOF-Derived Catalyst Using a Solvothermal Method: Effect on FTS Activity and Olefin Production.The design of a highly active Fe-supported catalyst with the optimum particle and pore size, dispersion, loading, and stability is essential for obtaining the desired product selectivity. This study employed a solvothermal method to prepare two Fe-MIL-88B metal-organic framework (MOF)-derived catalysts using triethylamine (TEA) or NaOH as deprotonation catalysts. The catalysts were analyzed using X-ray diffraction, N₂-physisorption, Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, H₂ temperature-programed reduction, and thermogravimetric analysis and were evaluated for the Fischer-Tropsch synthesis performance. It was evident that the catalyst preparation in the presence of TEA produces a higher MOF yield and smaller crystal size than those produced using NaOH. The pyrolysis of MOFs yielded catalysts with different Fe particle sizes of 6 and 35 nm for the preparation in the presence of TEA and NaOH, respectively. Also, both types of catalysts exhibited a high Fe loading (50%) and good stability after 100 h reaction time. The smaller particle size TEA catalyst showed higher activity and higher olefin yield, with 94% CO conversion and a higher olefin yield of 24% at a lower reaction temperature of 280 °C and 20 bar at H₂/CO = 1. Moreover, the smaller particle size TEA catalyst exhibited higher Fe time yield and CH₄ selectivity but with lower chain growth probability (α) and C₅₊ selectivity.2022-01-01T00:00:00Z2022 Mar2025-04-26T03:51:17.405Z2025-04-06T10:58:44.314ZS-EPMC89285323530943210.1021/acsomega.1c05927