{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Seijas-Da Silva A"],"funding":["Universitat de València","European Research Council","Ministerio de Ciencia e Innovación","Generalitat Valenciana"],"pagination":["4675-4684"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8939052"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["51(12)"],"pubmed_abstract":["Among the two-dimensional (2D) materials family, layered double hydroxides (LDHs) represent a key member due to their unparalleled chemical versatility. In particular, Fe-based LDHs are distinguished candidates due to their high efficiency as oxygen evolution reaction (OER) electrocatalysts. Herein, we have selected MgFe-based LDH phases as model systems in order to decipher whether Fe-clustering exerts an effect on the OER performance. For that, we have optimized hydrothermal synthesis by using triethanolamine (TEA) as the chelating agent. The magnetic characterisation allows us to identify the Fe-clustering degree by following both magnetic susceptibility as well as magnetization values at 2 K. Thanks to this, we demonstrated that TEA induces an increment in Fe-clustering. Electrochemica"],"journal":["Dalton transactions (Cambridge, England : 2003)"],"pubmed_title":["Influence of Fe-clustering on the water oxidation performance of two-dimensional layered double hydroxides."],"pmcid":["PMC8939052"],"funding_grant_id":["CIDEGENT/2018/001","788222","‘Atracción del talento’ predoctoral grant","Prometeo/2021/022","PDC2021-121106-I00","804110","ERC Advanced Grant Mol-2D 788222","ERC Starting Grant 2D-PnictoChem 804110","iDiFEDER/2018/061 co-financed by FEDER","PID2020-117152RB-I00 co-financed by FEDER","PID2019-111742GA-I00","Unit of Excellence “Maria de Maeztu” CEX2019-000919-M"],"pubmed_authors":["Coronado E","Oestreicher V","Abellan G","Seijas-Da Silva A"],"additional_accession":[]},"is_claimable":false,"name":"Influence of Fe-clustering on the water oxidation performance of two-dimensional layered double hydroxides.","description":"Among the two-dimensional (2D) materials family, layered double hydroxides (LDHs) represent a key member due to their unparalleled chemical versatility. In particular, Fe-based LDHs are distinguished candidates due to their high efficiency as oxygen evolution reaction (OER) electrocatalysts. Herein, we have selected MgFe-based LDH phases as model systems in order to decipher whether Fe-clustering exerts an effect on the OER performance. For that, we have optimized hydrothermal synthesis by using triethanolamine (TEA) as the chelating agent. The magnetic characterisation allows us to identify the Fe-clustering degree by following both magnetic susceptibility as well as magnetization values at 2 K. Thanks to this, we demonstrated that TEA induces an increment in Fe-clustering. Electrochemica","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Mar","modification":"2025-04-04T10:44:43.903Z","creation":"2025-04-04T10:44:43.903Z"},"accession":"S-EPMC8939052","cross_references":{"pubmed":["35212688"],"doi":["10.1039/d1dt03737d"]}}