<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>233(4)</volume><submitter>da Luz VC</submitter><pubmed_abstract>This study aimed to evaluate the implementation of an advanced oxidation system based on UV radiation and UV/H&lt;sub>2&lt;/sub>O&lt;sub>2&lt;/sub> for degradation of TCS and IBU in synthetic effluent. The assays occurred in a 2-L reactor, protected from external light and equipped with a UV lamp (&lt;i>λ&lt;/i> = 254 nm). The effect of contaminant concentration, fractions of chemical species present, and mineralization were evaluated. In the UV/ H&lt;sub>2&lt;/sub>O&lt;sub>2&lt;/sub> system, different concentrations of H&lt;sub>2&lt;/sub>O&lt;sub>2&lt;/sub> were studied for oxidation of the contaminants. The kinetic experiments took place between 75 and 270 min of UV irradiation. The results showed > 99% oxidation of TCS in the direct photolysis system at pH 9.4 after 12 min. The degradation of IBU in the UV/H&lt;sub>2&lt;/sub>O&lt;sub>2&lt;/sub> system, when 10 mg L&lt;sup>-1&lt;/sup> of H&lt;sub>2&lt;/sub>O&lt;sub>2&lt;/sub> was used, was 97.39% oxidation. We obtained &lt;i>k'&lt;/i> values of 0.189 min&lt;sup>-1&lt;/sup> for TCS when its highest oxidation occurred and &lt;i>k'&lt;/i> values of 0.0219 min&lt;sup>-1&lt;/sup> for IBU. The system was not able to completely mineralize the contaminants, presenting high values of TOC and COD after treatment, thus suggesting the occurrence of phototransformation.&lt;h4>Supplementary information&lt;/h4>The online version contains supplementary material available at 10.1007/s11270-022-05583-z.</pubmed_abstract><journal>Water, air, and soil pollution</journal><pagination>126</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC8975727</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Enhanced UV Direct Photolysis and UV/H&lt;sub>2&lt;/sub>O&lt;sub>2&lt;/sub> for Oxidation of Triclosan and Ibuprofen in Synthetic Effluent: an Experimental Study.</pubmed_title><pmcid>PMC8975727</pmcid><pubmed_authors>Dalla Rosa C</pubmed_authors><pubmed_authors>Bazoti SF</pubmed_authors><pubmed_authors>Pasquali GDL</pubmed_authors><pubmed_authors>da Luz VC</pubmed_authors><pubmed_authors>Behling L</pubmed_authors></additional><is_claimable>false</is_claimable><name>Enhanced UV Direct Photolysis and UV/H&lt;sub>2&lt;/sub>O&lt;sub>2&lt;/sub> for Oxidation of Triclosan and Ibuprofen in Synthetic Effluent: an Experimental Study.</name><description>This study aimed to evaluate the implementation of an advanced oxidation system based on UV radiation and UV/H&lt;sub>2&lt;/sub>O&lt;sub>2&lt;/sub> for degradation of TCS and IBU in synthetic effluent. The assays occurred in a 2-L reactor, protected from external light and equipped with a UV lamp (&lt;i>λ&lt;/i> = 254 nm). The effect of contaminant concentration, fractions of chemical species present, and mineralization were evaluated. In the UV/ H&lt;sub>2&lt;/sub>O&lt;sub>2&lt;/sub> system, different concentrations of H&lt;sub>2&lt;/sub>O&lt;sub>2&lt;/sub> were studied for oxidation of the contaminants. The kinetic experiments took place between 75 and 270 min of UV irradiation. The results showed > 99% oxidation of TCS in the direct photolysis system at pH 9.4 after 12 min. The degradation of IBU in the UV/H&lt;sub>2&lt;/sub>O&lt;sub>2&lt;/sub> system, when 10 mg L&lt;sup>-1&lt;/sup> of H&lt;sub>2&lt;/sub>O&lt;sub>2&lt;/sub> was used, was 97.39% oxidation. We obtained &lt;i>k'&lt;/i> values of 0.189 min&lt;sup>-1&lt;/sup> for TCS when its highest oxidation occurred and &lt;i>k'&lt;/i> values of 0.0219 min&lt;sup>-1&lt;/sup> for IBU. The system was not able to completely mineralize the contaminants, presenting high values of TOC and COD after treatment, thus suggesting the occurrence of phototransformation.&lt;h4>Supplementary information&lt;/h4>The online version contains supplementary material available at 10.1007/s11270-022-05583-z.</description><dates><release>2022-01-01T00:00:00Z</release><publication>2022</publication><modification>2026-03-18T13:41:19.552Z</modification><creation>2025-04-19T07:48:22.313Z</creation></dates><accession>S-EPMC8975727</accession><cross_references><pubmed>35400768</pubmed><doi>10.1007/s11270-022-05583-z</doi></cross_references></HashMap>