biostudies-literatureXu KNational Natural Science Foundation of ChinaChongqing Municipal Education Commission2712-2720https://www.ebi.ac.uk/biostudies/studies/S-EPMC8979244biostudies-literatureUnknown12(5)The integration of superior mechanical properties and fast healing efficiency for self-healing polyurethane supramolecular elastomers is challenging due to the confliction between high chain mobility for healing and high chain rigidity for mechanical properties. Herein, a strategy to design a "hard-soft" hard domain by the cooperation of quadruple hydrogen bonds (HBs) in the mainchain as restriction units and single HBs in the side chain as diffusion units is reported. The resulting transparent supramolecular elastomer exhibited fast self-recoverability, good puncture resistance and superior mechanical properties with a tensile strength of 20.5 MPa, an extensibility of 2043.7%, a toughness of 146.1 MJ m^-3 and a tear resistance of 13.8 kJ m^-2. Moreover, the fast self-hRSC advancesTransparent, self-recoverable, highly tough, puncture and tear resistant polyurethane supramolecular elastomer with fast self-healing capacity <i>via</i> "hard-soft" hard domain design.PMC8979244KJQN20200134551703016KJQN201801332Xu KZhao MHe WChen GPu YHu QfalseTransparent, self-recoverable, highly tough, puncture and tear resistant polyurethane supramolecular elastomer with fast self-healing capacity <i>via</i> "hard-soft" hard domain design.The integration of superior mechanical properties and fast healing efficiency for self-healing polyurethane supramolecular elastomers is challenging due to the confliction between high chain mobility for healing and high chain rigidity for mechanical properties. Herein, a strategy to design a "hard-soft" hard domain by the cooperation of quadruple hydrogen bonds (HBs) in the mainchain as restriction units and single HBs in the side chain as diffusion units is reported. The resulting transparent supramolecular elastomer exhibited fast self-recoverability, good puncture resistance and superior mechanical properties with a tensile strength of 20.5 MPa, an extensibility of 2043.7%, a toughness of 146.1 MJ m^-3 and a tear resistance of 13.8 kJ m^-2. Moreover, the fast self-h2022-01-01T00:00:00Z2022 Jan2025-04-26T15:15:31.167Z2025-04-06T14:53:41.62ZS-EPMC89792443542529710.1039/d1ra07083e