{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["12(9)"],"submitter":["Xin S"],"pubmed_abstract":["A tungsten containing catalyst catalyzed oxidative cleavage of methyl oleate (MO) by employing H<sub>2</sub>O<sub>2</sub> as an oxidant and is known as an efficient approach for preparing high value-added chemicals, however, the tungsten leaching problem remains unresolved. In this work, a binary catalyst consisting of tungsten oxide (WO<sub>3</sub>) and spongy titanosilicate (STS) zeolite is proposed for MO oxidative cleavage. The function of STS in this catalyst is investigated. On the one hand, STS converts MO to 9,10-epoxystearate (MES), which further forms nonyl aldehyde (NA) and methyl azelaaldehydate (MAA) with the catalysis of WO<sub>3</sub>. In this way, MO oxidation and hydrolysis that generates unwanted diol product 9,10-dihydroxystearate (MDS) decreases obviously. On the other "],"journal":["RSC advances"],"pagination":["5135-5144"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8981253"],"repository":["biostudies-literature"],"pubmed_title":["Spongy titanosilicate promotes the catalytic performance and reusability of WO<sub>3</sub> in oxidative cleavage of methyl oleate."],"pmcid":["PMC8981253"],"pubmed_authors":["Peng X","Huang Z","Zhang Y","Xin S","Zheng A","Xia C","Shu X","Zhu B","Lin M"],"additional_accession":[]},"is_claimable":false,"name":"Spongy titanosilicate promotes the catalytic performance and reusability of WO<sub>3</sub> in oxidative cleavage of methyl oleate.","description":"A tungsten containing catalyst catalyzed oxidative cleavage of methyl oleate (MO) by employing H<sub>2</sub>O<sub>2</sub> as an oxidant and is known as an efficient approach for preparing high value-added chemicals, however, the tungsten leaching problem remains unresolved. In this work, a binary catalyst consisting of tungsten oxide (WO<sub>3</sub>) and spongy titanosilicate (STS) zeolite is proposed for MO oxidative cleavage. The function of STS in this catalyst is investigated. On the one hand, STS converts MO to 9,10-epoxystearate (MES), which further forms nonyl aldehyde (NA) and methyl azelaaldehydate (MAA) with the catalysis of WO<sub>3</sub>. In this way, MO oxidation and hydrolysis that generates unwanted diol product 9,10-dihydroxystearate (MDS) decreases obviously. On the other ","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Feb","modification":"2025-04-26T15:14:21.575Z","creation":"2025-04-06T14:53:12.307Z"},"accession":"S-EPMC8981253","cross_references":{"pubmed":["35425581"],"doi":["10.1039/d1ra08501h"]}}