{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Thiel TA"],"funding":["Deutsche Forschungsgemeinschaft"],"pagination":["7055-7065"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8982184"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["12(12)"],"pubmed_abstract":["A previously developed sustainable immobilization concept for photocatalysts based on cellulose as a renewable support material was applied for the photocatalytic hydrogenation of acetophenone (ACP) to 1-phenyl ethanol (PE). Four different TiO<sub>2</sub> modifications (P25, P90, PC105, and PC500) were screened for the reaction showing good performance for PC25 and PC500. PC500 was selected for a detailed kinetic study to find the optimal operating conditions, and to obtain a better understanding of the photocatalytic pathway in relation to conventional and transfer hydrogenation. The kinetic data were analyzed using the pseudo-first-order reaction rate law. A complete conversion was obtained for ACP concentrations below 1 mM using a 360 nm filter and argon as the purge gas within 2-3 hour"],"journal":["RSC advances"],"pubmed_title":["Photocatalytic hydrogenation of acetophenone on a titanium dioxide cellulose film."],"pmcid":["PMC8982184"],"funding_grant_id":["390540038"],"pubmed_authors":["Obata K","Schwarze M","Thiel TA","Schomacker R","Abdi FF","van de Krol R"],"additional_accession":[]},"is_claimable":false,"name":"Photocatalytic hydrogenation of acetophenone on a titanium dioxide cellulose film.","description":"A previously developed sustainable immobilization concept for photocatalysts based on cellulose as a renewable support material was applied for the photocatalytic hydrogenation of acetophenone (ACP) to 1-phenyl ethanol (PE). Four different TiO<sub>2</sub> modifications (P25, P90, PC105, and PC500) were screened for the reaction showing good performance for PC25 and PC500. PC500 was selected for a detailed kinetic study to find the optimal operating conditions, and to obtain a better understanding of the photocatalytic pathway in relation to conventional and transfer hydrogenation. The kinetic data were analyzed using the pseudo-first-order reaction rate law. A complete conversion was obtained for ACP concentrations below 1 mM using a 360 nm filter and argon as the purge gas within 2-3 hour","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Mar","modification":"2025-04-04T07:34:42.169Z","creation":"2025-04-04T07:34:42.169Z"},"accession":"S-EPMC8982184","cross_references":{"pubmed":["35424704"],"doi":["10.1039/d1ra09294d"]}}