<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>78(Pt 4)</volume><submitter>Yennawar HP</submitter><pubmed_abstract>The crystal structure of racemic (&lt;i>R&lt;/i>/&lt;i>S&lt;/i>,&lt;i>E&lt;/i>)-2-(4-hy-droxy-phen-yl)-4-(2-phenyl-hydrazin-1-yl-idene)chromane-5,7-diol ethanol monosolvate, C&lt;sub>21&lt;/sub>H&lt;sub>18&lt;/sub>N&lt;sub>2&lt;/sub>O&lt;sub>4&lt;/sub>·C&lt;sub>2&lt;/sub>H&lt;sub>6&lt;/sub>O, in a centrosymmetric lattice is reported. The two racemates occupy the same position in the asymmetric unit - &lt;i>a disordered mixed enanti-omeric structure&lt;/i>. Hydrogen bonds of the type O-H⋯C(π) in addition to typical C-H⋯O, O-H⋯O and O-H⋯N are identified. A positional disorder is seen in the solvent mol-ecule (ethanol) as well. The phenyl-hydrazone group is nearly coplanar with the chromane ring system [dihedral angle = 15.5 (1)°], while the the 4-hy-droxy-phenyl ring is perpendicular [dihedral angle = 87.2 (1)°] to the chromane. The pyran ring has an</pubmed_abstract><journal>Acta crystallographica. Section E, Crystallographic communications</journal><pagination>346-348</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC8983983</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Crystal structure of racemic (&lt;i>R&lt;/i>/&lt;i>S&lt;/i>,&lt;i>E&lt;/i>)-2-(4-hy-droxy-phen-yl)-4-(2-phenyl-hydrazin-1-yl-idene)chromane-5,7-diol ethanol monosolvate.</pubmed_title><pmcid>PMC8983983</pmcid><pubmed_authors>Yennawar HP</pubmed_authors><pubmed_authors>Sigmon A</pubmed_authors></additional><is_claimable>false</is_claimable><name>Crystal structure of racemic (&lt;i>R&lt;/i>/&lt;i>S&lt;/i>,&lt;i>E&lt;/i>)-2-(4-hy-droxy-phen-yl)-4-(2-phenyl-hydrazin-1-yl-idene)chromane-5,7-diol ethanol monosolvate.</name><description>The crystal structure of racemic (&lt;i>R&lt;/i>/&lt;i>S&lt;/i>,&lt;i>E&lt;/i>)-2-(4-hy-droxy-phen-yl)-4-(2-phenyl-hydrazin-1-yl-idene)chromane-5,7-diol ethanol monosolvate, C&lt;sub>21&lt;/sub>H&lt;sub>18&lt;/sub>N&lt;sub>2&lt;/sub>O&lt;sub>4&lt;/sub>·C&lt;sub>2&lt;/sub>H&lt;sub>6&lt;/sub>O, in a centrosymmetric lattice is reported. The two racemates occupy the same position in the asymmetric unit - &lt;i>a disordered mixed enanti-omeric structure&lt;/i>. Hydrogen bonds of the type O-H⋯C(π) in addition to typical C-H⋯O, O-H⋯O and O-H⋯N are identified. A positional disorder is seen in the solvent mol-ecule (ethanol) as well. The phenyl-hydrazone group is nearly coplanar with the chromane ring system [dihedral angle = 15.5 (1)°], while the the 4-hy-droxy-phenyl ring is perpendicular [dihedral angle = 87.2 (1)°] to the chromane. The pyran ring has an</description><dates><release>2022-01-01T00:00:00Z</release><publication>2022 Apr</publication><modification>2025-04-05T14:43:01.196Z</modification><creation>2025-04-05T14:43:01.196Z</creation></dates><accession>S-EPMC8983983</accession><cross_references><pubmed>35492281</pubmed><doi>10.1107/S2056989022002079</doi></cross_references></HashMap>