{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Li LY"],"funding":["National Natural Science Foundation of China","Natural Science Foundation of Jiangsu Province"],"pagination":["8443-8448"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8984952"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["12(14)"],"pubmed_abstract":["An atom-economic method of preparing allylic sulfones <i>via</i> hydrosulfonylation of allenes with sulfinic acids under Pd(0)-catalysis was reported. This process has a high degree of regio- and stereoselectivity, and provides the target product with a moderate to excellent yield. A wide range of nitrogen- or oxygen-containing linear <i>E</i>-allylic sulfones have been synthesized. With the support of experimental research, a possible mechanism was proposed."],"journal":["RSC advances"],"pubmed_title":["Palladium-catalyzed regioselective hydrosulfonylation of allenes with sulfinic acids."],"pmcid":["PMC8984952"],"funding_grant_id":["21801130","BK20180689"],"pubmed_authors":["Wei P","Liu QQ","Li JZ","Yu J","Wang DC","Leng BR","Li LY","Zhu YL"],"additional_accession":[]},"is_claimable":false,"name":"Palladium-catalyzed regioselective hydrosulfonylation of allenes with sulfinic acids.","description":"An atom-economic method of preparing allylic sulfones <i>via</i> hydrosulfonylation of allenes with sulfinic acids under Pd(0)-catalysis was reported. This process has a high degree of regio- and stereoselectivity, and provides the target product with a moderate to excellent yield. A wide range of nitrogen- or oxygen-containing linear <i>E</i>-allylic sulfones have been synthesized. With the support of experimental research, a possible mechanism was proposed.","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Mar","modification":"2025-04-04T07:35:01.227Z","creation":"2025-04-04T07:35:01.227Z"},"accession":"S-EPMC8984952","cross_references":{"pubmed":["35424818"],"doi":["10.1039/d1ra09036d"]}}