{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["12(15)"],"submitter":["Feng S"],"pubmed_abstract":["Cyclohexanol and its derivatives are widely used as chemical intermediates and fuel additives. Herein, Ru/SBA-15 catalysts were prepared <i>via</i> impregnation, and used for the production of cyclohexanols from lignin-derived phenols. The catalyst samples were characterized by XRD, XPS, TEM, <i>etc.</i>, where the Ru<sup>0</sup> species was speculated as the active phase. 5 wt% Ru/SBA-15 with small Ru particle size (4.99 nm) and high Ru dispersion (27.05%) exhibited an excellent hydrogenation activity. A high cyclohexanol yield of >99.9% was achieved at 20 °C for 5 h in an aqueous phase, and the catalyst indicated stable activity and selectivity after five runs. Crucially, Ru/SBA-15 exhibited a zero-order reaction rate with an apparent activation energy (Ea) as low as 10.88 kJ mol<sup>-1<"],"journal":["RSC advances"],"pagination":["9352-9362"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8985087"],"repository":["biostudies-literature"],"pubmed_title":["Low temperature catalytic hydrodeoxygenation of lignin-derived phenols to cyclohexanols over the Ru/SBA-15 catalyst."],"pmcid":["PMC8985087"],"pubmed_authors":["Liu X","Li G","Hu C","Su Z","Feng S"],"additional_accession":[]},"is_claimable":false,"name":"Low temperature catalytic hydrodeoxygenation of lignin-derived phenols to cyclohexanols over the Ru/SBA-15 catalyst.","description":"Cyclohexanol and its derivatives are widely used as chemical intermediates and fuel additives. Herein, Ru/SBA-15 catalysts were prepared <i>via</i> impregnation, and used for the production of cyclohexanols from lignin-derived phenols. The catalyst samples were characterized by XRD, XPS, TEM, <i>etc.</i>, where the Ru<sup>0</sup> species was speculated as the active phase. 5 wt% Ru/SBA-15 with small Ru particle size (4.99 nm) and high Ru dispersion (27.05%) exhibited an excellent hydrogenation activity. A high cyclohexanol yield of >99.9% was achieved at 20 °C for 5 h in an aqueous phase, and the catalyst indicated stable activity and selectivity after five runs. Crucially, Ru/SBA-15 exhibited a zero-order reaction rate with an apparent activation energy (Ea) as low as 10.88 kJ mol<sup>-1<","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Mar","modification":"2025-04-19T12:58:46.484Z","creation":"2025-04-19T12:58:46.484Z"},"accession":"S-EPMC8985087","cross_references":{"pubmed":["35424881"],"doi":["10.1039/d2ra01183b"]}}