{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Motohashi K"],"funding":["JST-Mirai Program","Japan Society for the Promotion of Science"],"pagination":["5955"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC8993874"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["12(1)"],"pubmed_abstract":["Aiming development of the fast anion conductors, we proposed a new material design using flexible molecular cation as a host cation, and demonstrated it with fluoride ion conduction in NH<sub>4</sub>MgF<sub>3</sub> and (NH<sub>4</sub>)<sub>2</sub>MgF<sub>4</sub> based materials. Dominant fluoride ion conduction with relatively high conductivities of 4.8 × 10<sup>-5</sup> S cm<sup>-1</sup> and 8.4 × 10<sup>-6</sup> S cm<sup>-1</sup> were achieved at 323 K in (NH<sub>4</sub>)<sub>2</sub>(Mg<sub>0.85</sub>Li<sub>0.15</sub>)F<sub>3.85</sub> and NH<sub>4</sub>(Mg<sub>0.9</sub>Li<sub>0.1</sub>)F<sub>2.9</sub>, respectively. It is implied that the molecular cation in the host lattice can assist the anion conduction. Our findings suggest molecular cation-containing compounds can be attractive material groups for fast anion conductors."],"journal":["Scientific reports"],"pubmed_title":["Fast fluoride ion conduction of NH<sub>4</sub>(Mg<sub>1-x</sub>Li<sub>x</sub>)F<sub>3-x</sub> and (NH<sub>4</sub>)<sub>2</sub>(Mg<sub>1-x</sub>Li<sub>x</sub>)F<sub>4-x</sub> assisted by molecular cations."],"pmcid":["PMC8993874"],"funding_grant_id":["20J12230","JPMJMI18E2"],"pubmed_authors":["Kuwata N","Uchimoto Y","Kimura Y","Motohashi K","Amezawa K","Nakamura T","Matsukawa Y"],"additional_accession":[]},"is_claimable":false,"name":"Fast fluoride ion conduction of NH<sub>4</sub>(Mg<sub>1-x</sub>Li<sub>x</sub>)F<sub>3-x</sub> and (NH<sub>4</sub>)<sub>2</sub>(Mg<sub>1-x</sub>Li<sub>x</sub>)F<sub>4-x</sub> assisted by molecular cations.","description":"Aiming development of the fast anion conductors, we proposed a new material design using flexible molecular cation as a host cation, and demonstrated it with fluoride ion conduction in NH<sub>4</sub>MgF<sub>3</sub> and (NH<sub>4</sub>)<sub>2</sub>MgF<sub>4</sub> based materials. Dominant fluoride ion conduction with relatively high conductivities of 4.8 × 10<sup>-5</sup> S cm<sup>-1</sup> and 8.4 × 10<sup>-6</sup> S cm<sup>-1</sup> were achieved at 323 K in (NH<sub>4</sub>)<sub>2</sub>(Mg<sub>0.85</sub>Li<sub>0.15</sub>)F<sub>3.85</sub> and NH<sub>4</sub>(Mg<sub>0.9</sub>Li<sub>0.1</sub>)F<sub>2.9</sub>, respectively. It is implied that the molecular cation in the host lattice can assist the anion conduction. Our findings suggest molecular cation-containing compounds can be attractive material groups for fast anion conductors.","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Apr","modification":"2025-04-04T12:41:02.995Z","creation":"2025-04-04T12:41:02.995Z"},"accession":"S-EPMC8993874","cross_references":{"pubmed":["35396522"],"doi":["10.1038/s41598-022-09835-0"]}}