{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Wygant BR"],"funding":["U.S. Department of Energy's National Nuclear Security Administration","United States Government","Sandia National Laboratories","National Technology and Engineering Solutions of Sandia","Honeywell International, Inc."],"pagination":["e2105803"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9036002"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["9(12)"],"pubmed_abstract":["FeF<sub>3</sub> conversion cathodes, paired with Li metal, are promising for use in next-generation secondary batteries and offer a remarkable theoretical energy density of 1947 Wh kg<sup>-1</sup> compared to 690 Wh kg<sup>-1</sup> for LiNi<sub>0.5</sub> Mn<sub>1.5</sub> O<sub>4</sub> ; however, many successful studies on FeF<sub>3</sub> cathodes are performed in cells with a large (>90-fold) excess of Li that disguises the effects of tested variables on the anode and decreases the practical energy density of the battery. Herein, it is demonstrated that for full-cell compatibility, the electrolyte must produce both a protective solid-electrolyte interphase and cathode-electrolyte interphase and that an electrolyte composed of 1:1.3:3 (m/m) LiFSI, 1,2-dimethoxyethane, and 1,1,2,2-tetrafluor"],"journal":["Advanced science (Weinheim, Baden-Wurttemberg, Germany)"],"pubmed_title":["The Role of Electrolyte Composition in Enabling Li Metal-Iron Fluoride Full-Cell Batteries."],"pmcid":["PMC9036002"],"funding_grant_id":["DE-NA-0003525"],"pubmed_authors":["Harrison KL","Wygant BR","Merrill LC","Talin AA","Lambert TN","Ashby DS"],"additional_accession":[]},"is_claimable":false,"name":"The Role of Electrolyte Composition in Enabling Li Metal-Iron Fluoride Full-Cell Batteries.","description":"FeF<sub>3</sub> conversion cathodes, paired with Li metal, are promising for use in next-generation secondary batteries and offer a remarkable theoretical energy density of 1947 Wh kg<sup>-1</sup> compared to 690 Wh kg<sup>-1</sup> for LiNi<sub>0.5</sub> Mn<sub>1.5</sub> O<sub>4</sub> ; however, many successful studies on FeF<sub>3</sub> cathodes are performed in cells with a large (>90-fold) excess of Li that disguises the effects of tested variables on the anode and decreases the practical energy density of the battery. Herein, it is demonstrated that for full-cell compatibility, the electrolyte must produce both a protective solid-electrolyte interphase and cathode-electrolyte interphase and that an electrolyte composed of 1:1.3:3 (m/m) LiFSI, 1,2-dimethoxyethane, and 1,1,2,2-tetrafluor","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Apr","modification":"2025-04-04T22:17:07.974Z","creation":"2025-04-04T22:17:07.974Z"},"accession":"S-EPMC9036002","cross_references":{"pubmed":["35199953"],"doi":["10.1002/advs.202105803"]}}