{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["11(53)"],"submitter":["Wu B"],"pubmed_abstract":["Porous organic polymers (POPs), owing to their abundant porosity, high stability and well-tunable properties, are promising candidates as heterogeneous photocatalysts for organic transformations. Here we report two vinylene-bridged donor-acceptor (D-A) structural POPs (TpTc-POP and TbTc-POP) that are facilely constructed by the electron-rich triarylamine and electron-deficient tricyanomesitylene as key building blocks by the organic base catalyzed Knoevenagel condensation. Both TpTc-POP and TbTc-POP possess hierarchical meso- and micro-pores with a high surface area. Furthermore, the unsubstituted vinylene linkages of D-A moieties in their polymer backbones extend their π-conjugation and render their broad absorption range in the visible-light region. Thus, these DA-POPs exhibited highly e"],"journal":["RSC advances"],"pagination":["33653-33660"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9042297"],"repository":["biostudies-literature"],"pubmed_title":["Vinylene-bridged donor-acceptor type porous organic polymers for enhanced photocatalysis of amine oxidative coupling reactions under visible light."],"pmcid":["PMC9042297"],"pubmed_authors":["Liu Y","Li QY","Jiang X","Wu B","Wang XJ","Zhao X"],"additional_accession":[]},"is_claimable":false,"name":"Vinylene-bridged donor-acceptor type porous organic polymers for enhanced photocatalysis of amine oxidative coupling reactions under visible light.","description":"Porous organic polymers (POPs), owing to their abundant porosity, high stability and well-tunable properties, are promising candidates as heterogeneous photocatalysts for organic transformations. Here we report two vinylene-bridged donor-acceptor (D-A) structural POPs (TpTc-POP and TbTc-POP) that are facilely constructed by the electron-rich triarylamine and electron-deficient tricyanomesitylene as key building blocks by the organic base catalyzed Knoevenagel condensation. Both TpTc-POP and TbTc-POP possess hierarchical meso- and micro-pores with a high surface area. Furthermore, the unsubstituted vinylene linkages of D-A moieties in their polymer backbones extend their π-conjugation and render their broad absorption range in the visible-light region. Thus, these DA-POPs exhibited highly e","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021 Oct","modification":"2025-05-31T22:57:54.51Z","creation":"2025-05-31T22:57:54.51Z"},"accession":"S-EPMC9042297","cross_references":{"pubmed":["35497515"],"doi":["10.1039/d1ra06118f"]}}