{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["11(63)"],"submitter":["Wu J"],"pubmed_abstract":["The new hexagonal perovskite phase of composition Ba<sub>4</sub>Sn<sub>1.1</sub>Mn<sub>2.9</sub>O<sub>12</sub> has been synthesized by solid-state reactions at 1673 K. The crystal structure has been investigated using X-ray and neutron diffraction. The hexagonal perovskite structure has an ordered arrangement of Sn and Mn ions on the corner-sharing octahedral centers and the face-sharing octahedral centers respectively. Short Mn-Mn distances have been evidenced in the face-sharing trimer of MnO<sub>6</sub> octahedra. The magnetic susceptibility shows magnetic cluster behavior, with cluster formation temperature ∼220 K. Antiferromagnetic order has been observed at <i>T</i> <sub>N</sub> ∼ 6 K. Ba<sub>4</sub>Sn<sub>1.1</sub>Mn<sub>2.9</sub>O<sub>12</sub> is a semiconductor with a transport ac"],"journal":["RSC advances"],"pagination":["40235-40242"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9044838"],"repository":["biostudies-literature"],"pubmed_title":["Molecule-like cluster magnetism and cationic order in the new hexagonal perovskite Ba<sub>4</sub>Sn<sub>1.1</sub>Mn<sub>2.9</sub>O<sub>12</sub>."],"pmcid":["PMC9044838"],"pubmed_authors":["Wu J","Yin C","Guo W","Wang X","Kuang X","Yan X"],"additional_accession":[]},"is_claimable":false,"name":"Molecule-like cluster magnetism and cationic order in the new hexagonal perovskite Ba<sub>4</sub>Sn<sub>1.1</sub>Mn<sub>2.9</sub>O<sub>12</sub>.","description":"The new hexagonal perovskite phase of composition Ba<sub>4</sub>Sn<sub>1.1</sub>Mn<sub>2.9</sub>O<sub>12</sub> has been synthesized by solid-state reactions at 1673 K. The crystal structure has been investigated using X-ray and neutron diffraction. The hexagonal perovskite structure has an ordered arrangement of Sn and Mn ions on the corner-sharing octahedral centers and the face-sharing octahedral centers respectively. Short Mn-Mn distances have been evidenced in the face-sharing trimer of MnO<sub>6</sub> octahedra. The magnetic susceptibility shows magnetic cluster behavior, with cluster formation temperature ∼220 K. Antiferromagnetic order has been observed at <i>T</i> <sub>N</sub> ∼ 6 K. Ba<sub>4</sub>Sn<sub>1.1</sub>Mn<sub>2.9</sub>O<sub>12</sub> is a semiconductor with a transport ac","dates":{"release":"2021-01-01T00:00:00Z","publication":"2021 Dec","modification":"2025-04-04T23:15:25.846Z","creation":"2025-04-04T23:15:25.846Z"},"accession":"S-EPMC9044838","cross_references":{"pubmed":["35494139"],"doi":["10.1039/d1ra07841k"]}}