{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Liu Y"],"funding":["Fundamental Research Funds for the Central Universities","Natural Science Foundation of Shanghai"],"pagination":["1219-1225"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9048752"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["10(3)"],"pubmed_abstract":["In this study, we have developed a continuous-flow electrochemical system towards the rapid and selective conversion of ammonia to N<sub>2</sub>, based on a tubular substoichiometric titanium dioxide (Ti<sub>4</sub>O<sub>7</sub>) anode and a Pd-Cu co-modified Ni foam (Pd-Cu/NF) cathode, both of which are indispensable. Under the action of a suitable anode potential, the Ti<sub>4</sub>O<sub>7</sub> anode enables the conversion of Cl<sup>-</sup> to chloride radicals (Cl˙), which could selectively react with ammonia to produce N<sub>2</sub>. The anodic byproducts, <i>e.g.</i> NO<sub>3</sub> <sup>-</sup>, were further reduced to N<sub>2</sub> at the Pd-Cu/NF cathode. EPR and scavenger experiments confirmed the dominant role of Cl˙ in ammonia conversion. Complete transformation of 30 mg L<sup>-"],"journal":["RSC advances"],"pubmed_title":["Rapid and selective electrochemical transformation of ammonia to N<sub>2</sub> by substoichiometric TiO<sub>2</sub>-based electrochemical system."],"pmcid":["PMC9048752"],"funding_grant_id":["18ZR1401000","2232019G-11"],"pubmed_authors":["Liu Y","Mei J","Yang M","Sand W","Li F","Huang M","Shen C","Wang Z"],"additional_accession":[]},"is_claimable":false,"name":"Rapid and selective electrochemical transformation of ammonia to N<sub>2</sub> by substoichiometric TiO<sub>2</sub>-based electrochemical system.","description":"In this study, we have developed a continuous-flow electrochemical system towards the rapid and selective conversion of ammonia to N<sub>2</sub>, based on a tubular substoichiometric titanium dioxide (Ti<sub>4</sub>O<sub>7</sub>) anode and a Pd-Cu co-modified Ni foam (Pd-Cu/NF) cathode, both of which are indispensable. Under the action of a suitable anode potential, the Ti<sub>4</sub>O<sub>7</sub> anode enables the conversion of Cl<sup>-</sup> to chloride radicals (Cl˙), which could selectively react with ammonia to produce N<sub>2</sub>. The anodic byproducts, <i>e.g.</i> NO<sub>3</sub> <sup>-</sup>, were further reduced to N<sub>2</sub> at the Pd-Cu/NF cathode. EPR and scavenger experiments confirmed the dominant role of Cl˙ in ammonia conversion. Complete transformation of 30 mg L<sup>-","dates":{"release":"2020-01-01T00:00:00Z","publication":"2020 Jan","modification":"2025-04-19T12:58:15.068Z","creation":"2025-04-19T12:58:15.068Z"},"accession":"S-EPMC9048752","cross_references":{"pubmed":["35494680"],"doi":["10.1039/c9ra07470h"]}}